عنوان

An in-situ Experimental Investigation of the Interrelationship between Wettability and Oil Recovery during Low-Salinity Waterflooding

شماره

TLpq2436433435

زبان متن نوشتاري يا گفتاري و مانند آن

انگلیسی

عنوان اصلي

An in-situ Experimental Investigation of the Interrelationship between Wettability and Oil Recovery during Low-Salinity Waterflooding

نام عام مواد

[Thesis]

نام نخستين پديدآور

Xie, Yun

نام ساير پديدآوران

Piri, Mohammad

نام ناشر، پخش کننده و غيره

University of Wyoming

تاریخ نشرو بخش و غیره

2020

نام خاص و کميت اثر

209

جزئيات پايان نامه و نوع درجه آن

Ph.D.

کسي که مدرک را اعطا کرده

University of Wyoming

امتياز متن

2020

متن يادداشت

Wettability reversal during the displacement processes encountered in hydrocarbon reservoirs has gained significant attention in recent years owing to its critical role in the success/failure of water-based enhanced oil recovery (EOR) schemes. Regardless of different designations used for these technologies, e.g., low-salinity waterflooding (LSWF), smart water injection, or engineered water injection, manipulating the ionic compositions and concentrations of the aqueous solutions to trigger the wettability reversal process is the shared objective. Despite the encouraging application potentials, the mechanisms that govern the wettability reversal and how it affects the displacement efficiency are still poorly understood, particularly in oil-wet carbonates. Therefore, in this work, multi-scale experiments were carefully designed and conducted to probe the impacts of rock wettability and its reversal, induced through brine chemistry manipulation, on oil recovery performance. We first investigated the adsorption-controlled calcite substrate wettability using a HPHT interfacial tension/contact angle measurement apparatus. The results were then further examined in natural rock samples through miniature core-flooding experiments. A high-resolution X-ray micro-CT scanner was used with a multiphase fluid delivery system to conduct the flow tests. Prior to each waterflooding experiment, an equilibrium wettability state was established in the core sample. This study reveals that wettability reversal, caused by adsorption/desorption of the polar components present in crude oil, is the principal factor responsible for the changes in oil recovery trend during LSWF. Dynamic contact angles measured on calcite substrates indicated that adsorption of the polar components controlled the surface wettability. Higher concentrations of Ca2+/SO42− can facilitate/obstruct the adsorption of polar components thus increase/decrease the dynamic contact angle values. A similar wetting strength sensitivity to the changes in aqueous phase composition was observed in miniature core samples when the in-situ contact angle measurement technique was used to characterize wettability. Using a dynamic aging process, weakly to strongly oil-wet conditions were established in samples aged with high-salinity brine, whereas low-salinity brine or brine with a higher concentration of sulfate ions created a more heterogeneous wettability. Different equilibrium wetting conditions thus produced various oil recovery trends. Moreover, two distinct displacement mechanisms, i.e., piston-like invasion and wetting oil layer drainage, were identified, through image analysis, to play key roles in affecting the recovery trends. Wettability reversal improved the efficiency of water-displacing-oil events by enhancing the frequency/strength of both mechanisms, while their relative contributions varied from one wettability case to another. These findings provide in-situ experimental evidence that demonstrates a direct link between the composition of the engineering injection brine and enhanced sweep efficiency at the pore scale in oil-wet carbonate samples.

موضوع مستند نشده

Engineering

موضوع مستند نشده

Petroleum engineering

مستند نام اشخاص تاييد نشده

Piri, Mohammad

مستند نام اشخاص تاييد نشده

Xie, Yun

نام الکترونيکي

فرمت انتشار

p

نوع ماده

[Thesis]

کد کاربرگه

276903

سطح دسترسي

a

تكميل شده

Y