Özgün yöntemler ile perovskit ince filmlerin imalatı ve karakterizasyonu
نام عام مواد
[Thesis]
نام نخستين پديدآور
Bıyıklı, Ozan
نام ساير پديدآوران
Sarı, Emre
وضعیت نشر و پخش و غیره
نام ناشر، پخش کننده و غيره
Izmir Institute of Technology (Turkey)
تاریخ نشرو بخش و غیره
2020
يادداشت کلی
متن يادداشت
85 p.
یادداشتهای مربوط به پایان نامه ها
جزئيات پايان نامه و نوع درجه آن
Master's
کسي که مدرک را اعطا کرده
Izmir Institute of Technology (Turkey)
امتياز متن
2020
یادداشتهای مربوط به خلاصه یا چکیده
متن يادداشت
Perovskite photovoltaics is a promising technology due to its low-cost fabrication and high efficiency. Since their first demonstration in 2009, efficiencies of perovskite solar cells (PSCs) increased unprecedently fast from 3.81% to 25.2% in 10 years. The most common method for the deposition of the absorber layer of the perovskite solar cells is the spin-coating method, which is not a scalable method, and this method is an obstacle to their commercialization. Efficiencies obtained with scalable methods are currently lower than that of the spin-coating method. In this thesis, among the scalable deposition methods, a novel ultrasonic spray-coating was used by adding antisolvent vapor to the system. The antisolvent quenching technique, that is commonly used to improve the crystalline quality of the film by spin-coating was successfully adapted for ultrasonic spray coating. The interaction between diethyl ether (DE) vapor, which is used as an antisolvent, and MAPb(I(3-x)Brx)3 precursor solution (where the solvent is DMF:DMSO, 4:1) was utilized to improve the crystalline quality of the perovskite film. As a result of this interaction, the intermediate phase was observed. The transition to the intermediate phase is supported by data from characterization methods such as optical microscopy, scanning electron microscopy (SEM), X-Ray diffraction (XRD), and current-voltage measurement. Furthermore, n-i-p devices with the FTO/c-TiO2/m-TiO2/MAPb(I(1-x)Brx)3/Spiro-OMeTAD architecture were produced with different antisolvent vapors and their efficiencies was compared. It was observed that devices using DE vapor reach higher efficiencies than devices without any antisolvent vapor.
اصطلاحهای موضوعی کنترل نشده
اصطلاح موضوعی
Alternative energy sources
اصطلاح موضوعی
Bias
اصطلاح موضوعی
Engineering
اصطلاح موضوعی
Fossil fuels
اصطلاح موضوعی
Photovoltaic cells
اصطلاح موضوعی
Semiconductors
نام شخص به منزله سر شناسه - (مسئولیت معنوی درجه اول )