عنوان

On-surface synthesis II :

شابک

3319758101

شابک

9783319758107

شابک اشتباه

3319758098

شابک اشتباه

9783319758091

عنوان اصلي

On-surface synthesis II :

نام عام مواد

[Book]

ساير اطلاعات عنواني

proceedings of the International Workshop On-Surface Synthesis, San Sebastián, 27-30 June 2016 /

نام نخستين پديدآور

Dimas G. de Oteyza, Celia Rogero, editors.

محل نشرو پخش و غیره

Cham, Switzerland :

نام ناشر، پخش کننده و غيره

Springer,

تاریخ نشرو بخش و غیره

2018.

نام خاص و کميت اثر

1 online resource (viii, 227 pages)

عنوان فروست

Advances in atom and single molecule machines,

شاپا ي ISSN فروست

2193-9691

متن يادداشت

Intro; Preface; Contents; 1 Mechanistic Insights into Surface-Supported Chemical Reactions; Abstract; 1 Introduction; 2 Imaging and Counting Intermediates; 3 Why Are Intermediates Stabilized?; 4 Bringing It All Together; 5 Outlook; Acknowledgements; References; 2 Kinetic and Thermodynamic Considerations in On-Surface Synthesis; Abstract; 1 Introduction; 2 Dehydrogenation Reactions; 3 Entropy of Desorbed Hydrogen Molecules; 4 Electrocyclic Ring-Closure Reaction; 5 C-H Activation and Coupling of Porphyrins; 6 Reaction Intermediates Stabilized by Surface Dissipation and Translational Entropy.

متن يادداشت

2.2 On-Surface Dehydrogenative Homocoupling2.3 Sequential C-X Groups Activation; 3 Summary and Outlook; References; 5 On-Surface Ullmann Reaction for the Synthesis of Polymers and Macrocycles; Abstract; 1 Introduction; 2 Synthesis of Polymers via Surface Ullmann Reaction; 2.1 The Emergence of the On-Surface Ullmann Reaction; 2.2 Identification of Organometallic Intermediates on Surfaces; 2.3 Stabilization of Organometallic Chains; 2.4 Dynamics of the Formation of Organometallic Chains; 2.5 Formation of Covalent Polymers; 3 Synthesis of Macrocycles via Surface Ullmann Reaction.

متن يادداشت

3.1 Cyclisation via Ring-Closure on a Surface3.2 Formation of Organometallic Macrocycles; 3.3 Formation of Covalent Macrocycles; 4 Summary; References; 6 Bottom-Up Fabrication of Atomically Precise Graphene Nanoribbons; Abstract; 1 Introduction; 2 Synthesis; 3 Characterization Tools and Associated Insight; 3.1 Electronic Properties Determination; 3.2 Chemical Structure; 3.3 Detection of Vibrational Modes; 4 Tuning the Electronic Properties; 4.1 Tuning Through Edge Orientation; 4.2 Tuning Through Width Control; 4.3 Tuning Through Doping; 4.4 Tuning Through Strain.

متن يادداشت

4.5 Tuning Through Heterostructure Formation5 Applications; Acknowledgements; References; 7 Aryl-Aryl Covalent Coupling on Rutile TiO2 Surfaces; Abstract; 1 Introduction; 2 TiO2 Properties; 2.1 General; 2.2 Comparison Between Rutile Faces; 2.3 Crystal Reduction and Surface Defects; 3 Aryl Halide Coupling on the Rutile (011) Surface; 3.1 First Successful C-C Coupling on a Rutile Surface; 3.2 Insight into Aryl Halide Coupling on the Rutile (011) Surface (Adapted from Ref. [18] with Permission from the Royal Chemical Society); 4 Aryl Halide Coupling on the Rutile (110) Surface.

متن يادداشت

7 Summary and OutlookReferences; 3 Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reveals; Abstract; 1 Introduction; 2 Chemical Reactivity; 2.1 Synthesis of Imines; 2.2 Other Reactions; 3 Photochemical Reactivity; 4 Electrochemical Reactivity; 5 Tip-Induced Reactivity; 6 Graphene Manipulation and Grafting; 7 Summary and Conclusions; Acknowledgements; References; 4 Dehydrogenative and Dehalogenative Homocoupling Reactions of C-X Groups on Metal Surfaces; Abstract; 1 Introduction; 2 Results and Discussions; 2.1 On-Surface Dehalogenative Homocoupling.

بدون عنوان

0

بدون عنوان

8

بدون عنوان

8

بدون عنوان

8

بدون عنوان

8

متن يادداشت

On-surface synthesis is appearing as an extremely promising strategy to create organic nanoarchitectures with atomic precision. Molecular building blocks holding adequate functional groups are dosed onto surfaces that support or even drive their covalent linkage. The surface confinement and the frequent lack of solvents (most commonly being performed under vacuum conditions) create a completely new scenario fully complementary to conventional chemistry. In a pedagogical way and based on the most recent developments, this volume presents our current understanding in the field, addressing fundamental reaction mechanisms, synthetic strategies to influence the reactions according to our needs, as well as the ultimate growth and characterization of functional materials. Verging on chemistry, physics and materials science, the book is aimed at students and researchers interested in nanochemistry, surface science, supramolecular materials and molecular devices. Chapters "Mechanistic insights into surface-supported chemical reactions", "Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reviels" and "Bottom-up fabrication of atomically precise graphene nanoribbons" of this book are available open access under a CC BY 4.0 license at link.springer.com.

منبع سفارش / آدرس اشتراک

Springer Nature

شماره انبار

com.springer.onix.9783319758107

عنوان

On-surface synthesis II.

شماره استاندارد بين المللي کتاب و موسيقي

9783319758091

عنوان اصلي به زبان ديگر

On-surface synthesis 2

موضوع مستند نشده

Nanochemistry, Congresses.

موضوع مستند نشده

Nanostructured materials, Congresses.

موضوع مستند نشده

Self-assembly (Chemistry), Congresses.

موضوع مستند نشده

Surface chemistry, Congresses.

موضوع مستند نشده

Materials science.

موضوع مستند نشده

Nanochemistry.

موضوع مستند نشده

Nanostructured materials.

موضوع مستند نشده

Nanotechnology.

موضوع مستند نشده

Organic chemistry.

موضوع مستند نشده

Polymer chemistry.

موضوع مستند نشده

Quantum & theoretical chemistry.

موضوع مستند نشده

SCIENCE-- Chemistry-- Physical & Theoretical.

موضوع مستند نشده

Self-assembly (Chemistry)

موضوع مستند نشده

Surface chemistry.

موضوع مستند نشده

SCI-- 013050

موضوع مستند نشده

TBN

شماره

ويراست

شماره رده

مستند نام اشخاص تاييد نشده

Oteyza, Dimas G. de

مستند نام اشخاص تاييد نشده

Rogero, Celia

مستند نام تنالگان تاييد نشده

International Workshop On-Surface Synthesis(2016 :, San Sebastián, Spain)

تاريخ عمليات

20200823110332.0

قواعد فهرست نويسي ( بخش توصيفي )

pn

نام الکترونيکي

نوع ماده

[Book]

تكميل شده

Y