Influence of Porosity, Permeability, and Pore Size Distribution on Storability, Injectivity, and Seal Efficiency of Carbonate Reservoirs and Shale Caprock: A Multi-Technique Approach for Geologic Carbon Sequestration
General Material Designation
[Thesis]
First Statement of Responsibility
Medina, Cristian Rodrigo
Subsequent Statement of Responsibility
Brassell, Simon
.PUBLICATION, DISTRIBUTION, ETC
Name of Publisher, Distributor, etc.
Indiana University
Date of Publication, Distribution, etc.
2019
GENERAL NOTES
Text of Note
152 p.
DISSERTATION (THESIS) NOTE
Dissertation or thesis details and type of degree
Ph.D.
Body granting the degree
Indiana University
Text preceding or following the note
2019
SUMMARY OR ABSTRACT
Text of Note
The successful implementation of geologic carbon sequestration depends on the careful evaluation of the petrophysical characteristics of the storage reservoir. Two petrophysical properties, porosity and permeability, constrain the reservoir in terms of its storage potential and injectivity. These two key parameters may vary significantly in scale within a reservoir. Likewise, the analytical tools that are useful for measuring these properties also vary and only assess pores of a given scale. In this investigation, a total of 52 rock samples that consist of carbonates having a high degree of dolomitization were obtained from the Cambrian-Ordovician Knox Supergroup from different depth intervals; these samples span a significant area of the midwestern United States.The samples were analyzed for total porosity and pore-size distribution using a variety of techniques including petrographic image analysis, helium porosimetry, gas adsorption, mercury porosimetry, and (ultra)-small-angle neutron scattering. Capillary entrapment,or "residual saturation," is that portion of the injected CO2 that remains trapped in micropores after the pressure elevated by the injection process returns to ambient reservoir pressure. Results from low-pressure nitrogen and carbon dioxide adsorption and from mercury injection capillary pressure are important in that they provide insights on small pore-sizethat otherwise cannot be resolvedby standard helium porosimetry or by image analysis software. Results from these analyses suggest that micro-, meso-, and macroporosity (~0-35 nm as suggested by gas adsorption and ~0.0025-100 μm as suggested by mercury porosimetry) are the main controlling factors of capillary entrapment and permeability, respectively.