BASIC CONCEPTS AND PRINCIPLES Definitions Intermolecular Bond Types on Organometallic Supramolecular Systems References MOLECULAR RECOGNITION AND HOST-GUEST INTERACTIONS Organometallic Receptors and their Host-Guest Complexes Organometallic Guests References SUPRAMOLECULAR SELF-ASSEMBLY THROUGH DATIVE BONDS (ELECTRON-PAIR DONOR-ACCEPTOR OR LEWIS ACID-BASE INTERACTIONS) Group 12 Metals: Zinc, Cadmium, Mercury Group 13 Metals: Aluminium, Gallium, Indium, Thallium Group 14 Metals: Tin and Lead References SUPRAMOLECULAR SELF-ASSEMBLY THROUGH SECONDARY BONDS Homoatomic Interactions Group 12 Metals: Zinc, Cadmium, Mercury Group 13 Metals: Gallium, Indium, Thallium Group 14 Metals: Tin and Lead Group 15 Metals: Arsenic, Antimony, Bismuth Group 16 Metals: Selenium and Tellurium References SUPRAMOLECULAR SELF-ASSEMBLY THROUGH HYDROGEN BOND INTERACTIONS Introduction Group 14 Elements: Silicon, Germanium, Tin, Lead Group 15 Elements: Arsenic, Antimony, Bismuth Transition Metals (Organometallic Crystal Engineering) References SUPRAMOLECULAR SELF-ASSEMBLY THROUGH IONIC INTERACTIONS Alkali Metals Alkali Earth Metals References SUPRAMOLECULAR SELF-ASSEMBLY THROUGH PI-INTERACTIONS Main Group Elements Transition Elements f-Elements References