The alkaline hydrolysis of esters in aqueous-organic solvent mixtures :
نام عام مواد
[Thesis]
نام نخستين پديدآور
Kazempour, Abdol Rassoul
عنوان اصلي به قلم نويسنده ديگر
the effects of solvents and of the activity coefficients of reactants on the kinetics of the alkaline hydrolysis of methyl acetate in aqueous dioxan, aqueous dimethyl sulphoxide and aqueous diglyme (bis (2-methoxyethyl ) ether) mixtures as solvents
نام ساير پديدآوران
Diaper, John
وضعیت نشر و پخش و غیره
نام ناشر، پخش کننده و غيره
University of Bradford
تاریخ نشرو بخش و غیره
1978
یادداشتهای مربوط به پایان نامه ها
جزئيات پايان نامه و نوع درجه آن
Thesis (Ph.D.)
امتياز متن
1978
یادداشتهای مربوط به خلاصه یا چکیده
متن يادداشت
Values of the rate constant for the alkaline hydrolysis of methyl acetate in various aqueous-organic solvent mixtures (dimethyl sulfoxide 0 aH 20> YOH_/YM+ -> (dielectric constant), and that the nonelectrostatic effects -- thermodynamic effects - are more important in these studies than the electrostatic effects. From a preliminary investigation of the data in the literature the thermodynamic approach also yields a valid interpretation of the effect of solvent composition on the rates of the acid hydrolysis of esters.