عنوان

The Chemistry of Linear Oligopyrroles and Bile Pigments

شابک

3709169380

شابک

9783709169384

شماره

b587279

عنوان اصلي

The Chemistry of Linear Oligopyrroles and Bile Pigments

نام عام مواد

[Book]

نام نخستين پديدآور

by Heinz Falk.

محل نشرو پخش و غیره

Vienna

نام ناشر، پخش کننده و غيره

Springer Vienna

تاریخ نشرو بخش و غیره

1989

نام خاص و کميت اثر

(xi, 621 pages 344 illustrations)

عنوان فروست

Monatshefte für Chemie/Chemical Monthly Supplementa, 1.

متن يادداشت

1. Introduction.- 2. Nomenclature.- 3. Occurrence, Formation, and Importance.- 4. Historical Aspects.- 5. Structure and Stereochemistry.- 5.1. General Considerations.- 5.1.1. Definitions.- Constitution.- Tautomerism.- Configuration.- Conformation.- Association.- 5.1.2. Energetics, Interconversions, Interdependencies.- 5.1.3. Methods of Structural Analysis.- Crystalline Materials.- Amorphous Materials.- Solutions.- 5.1.4. Principal Considerations on Structural Aspects of Linear Oligopyrroles.- Bipyrroles.- Bipyrrolylidenes.- Dipyrrins (Pyrromethenes).- Dipyrrinones (Pyrromethenones).- 5,10-Dihydrodipyrrins (Dipyrrylmethanes).- Dihydrodipyrrinones (Dihydropyrromethenones).- Tetrahydrodipyrrinones (Tetrahydropyrromethenones).- Prodigiosenes.- Tripyrrinones.- 1,19-Dioxobilins.- Dihydrobilins: 1,19-Dioxobiladienes-ac.- Dihydrobilins: 1,19-Dioxobiladienes-ab.- Dihydrobilins:1,19-Dioxo-2,3-dihydrobilins.- Tetrahydrobilins: 1,19-Dioxobilenes-b.- Tetrahydrobilins: 1,19-Dioxo-2,3-dihydrobiladienes-ab.- Hexahydrobilins: 1,19-Dioxobilanes.- Hexahydrobilins: Bilanes.- Secocorrins.- 1,19-Dioxo-10-nor-bilins and 1,19-Dioxo-10-nor-biladienes-ac.- Pentapyrrins.- 5.2. Structural Aspects of Linear Dipyrroles.- 5.2.1. Bipyrroles, Bipyrrolylidenes, and Analoga.- 5.2.2. Dipyrrins (Pyrromethenes).- 5.2.3. Dipyrrinones (Pyrromethenones) and Analoga.- 5.2.4. 5,10-Dihydrodipyrrins (Dipyrrylmethanes).- 5.2.5. Dihydrodipyrrinones (Dihydropyrromethenones).- 5.2.6. Tetrahydrodipyrrinones (Tetrahydropyrromethenones).- 5.3. Structural Aspects of Linear Tripyrroles.- 5.3.1. Terpyrroles.- 5.3.2. Prodigiosenes.- 5.3.3. Tripyrrinones and Analoga.- 5.4. Structural Aspects of Linear Tetrapyrroles.- 5.4.1. 1,19-Dioxobilins and Bilins.- 5.4.2. Dihydrobilins: 1,19-Dioxo-2,3-dihydrobilins.- 5.4.3. Dihydrobilins: 1,19-Dioxobiladienes-ac.- 5.4.4. Dihydrobilins: 1,19-Dioxobiladienes-ab.- 5.4.5. Tetrahydrobilins: 1,19-Dioxo-2,3-dihydrobiladienes-ab.- 5.4.6. Tetrahydrobilins: 1,19-Dioxobilenes-b.- 5.4.7. Tetrahydrobilins: Secocorphins.- 5.4.8. Hexa- and Octahydrobilins.- 5.4.9. Secocorrins.- 5.4.10. 1,19-Dioxo-l0-nor- Bilins and Biladienes-ac.- 5.5. Structural Aspects of Linear Oligopyrroles Containing Five or More Rings.- 5.5.1. Pentapyrrins.- 5.5.2. Hexapyrrins and Higher Homologues.- 5.5.3. Polypyrrole.- 6. Synthesis.- 6.1. Principal Considerations.- 6.2. Synthesis of Linear Dipyrroles.- 6.2.1. Bipyrroles, Bipyrrolylidenes, and Analoga.- 6.2.2. Dipyrrins (Pyrromethenes) and Analoga.- 6.2.3. Dipyrrinones (Pyrromethenones) and Analoga.- 6.2.4. 5,10-Dihydrodipyrrins (Dipyrrylmethanes).- 6.2.5. Dihydrodipyrrinones (Dihydropyrromethenones).- 6.2.6. Tetrahydrodipyrrinones (Tetrahydropyrromethenones).- 6.2.7. Miscellaneous Dipyrroles.- 6.3. Synthesis of Linear Tripyrroles.- 6.4. Synthesis of Linear Tetrapyrroles.- 6.4.1. 1,19-Dioxobilins and Bilins.- 6.4.2. Dihydrobilins: 1,19-Dioxo-2,3-dihydrobilins.- 6.4.3. Dihydrobilins: 1,19-Dioxobiladienes-ac.- 6.4.4. Dihydrobilins: 1,19-Dioxobiladienes-ab.- 6.4.5. Tetrahydrobilins: 1,19-Dioxo-2,3-dihydrobiladienes-ab.- 6.4.6. Tetrahydrobilins: 1,19-Dioxobilenes-b.- 6.4.7. Tetrahydrobilins: Secocorphins.- 6.4.8. Hexahydrobilins and Octahydrobilins.- 6.4.9. Secocorrins.- 6.4.10. 1,19-Dioxo-l0-nor- Bilins and Biladienes-ac.- 6.5. Synthesis of Linear Pentapyrroles and Higher Homologues.- 6.6. Transformations of Functional Groups Attached to Linear Oligopyrroles.- 7. Selected Physical Properties.- 7.1. Crystallization, Melting, Solubility.- 7.2. Light Absorption.- 7.3. Chiroptical Properties.- 7.4. Light Emission.- 7.5. Vibrational Spectroscopy.- 7.6. Nuclear Magnetic Resonance.- 7.7. Mass Spectra.- 8. Reactions.- 8.1. Photochemistry.- 8.2. Protonation - Deprotonation.- 8.3. Coordination (Carrier Mediated Transport).- 8.4. Nucleophilic, Electrophilic, and Radical Reactivity of Linear Oligopyrroles.- 8.5. Substitution Reactions.- 8.6. Addition Reactions.- 8.7. Skeletal Transformations.- 8.8. Reduction - Oxidation.- 8.9. Linear Oligopyrroles as Catalysts.- References.- Author Index.

موضوع مستند نشده

Chemistry, Organic.

موضوع مستند نشده

Chemistry.

موضوع مستند نشده

Physical organic chemistry.

مستند نام اشخاص تاييد نشده

by Heinz Falk.

مستند نام اشخاص تاييد نشده

Heinz Falk

نام الکترونيکي

نوع ماده

[Book]

تكميل شده

Y