عنوان

Organomagnesium methods in organic synthesis /

شابک

0127309454

شابک

9780127309453

شماره

dltt

عنوان اصلي

Organomagnesium methods in organic synthesis /

نام عام مواد

[Book]

نام نخستين پديدآور

Basil J. Wakefield

نام خاص و کميت اثر

xvi, 249 pages :

ساير جزييات

illustrations ;

ابعاد

24 cm

عنوان فروست

Best synthetic methods

متن يادداشت

Includes bibliographical references and index

متن يادداشت

The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes. Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined. Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided. Key Features * Presents a general overview of the constitution and reactivity of organomagnesium compounds * Provides coverage on the detection and estimation of organomagnesium compounds * Emphasizes practical aspects as well as principles * Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes * Includes preparations by metallation and metal-halogen exchanges * Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes * Outlines information on synthetically useful reactions of organomagnesium compounds * Describes the formation of carbon-heteroatom bonds in organic compounds * Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds * Includes representative procedures and tables with references to well-described examples

عنوان

Organomagnesium methods in organic synthesis.

موضوع مستند نشده

Organic compounds-- Synthesis

موضوع مستند نشده

Organomagnesium compounds

شماره

ويراست

شماره رده

نشانه اثر

مستند نام اشخاص تاييد نشده

Wakefield, B. J., (Basil John),1934-

تاريخ عمليات

20160712061501.0

نام الکترونيکي

نوع ماده

[Book]

تكميل شده

Y