عنوان

Concise Chemical Thermodynamics

940112390X

9789401123907

b556491

Concise Chemical Thermodynamics

[Book]

by J.R.W. Warn.

Dordrecht

Springer Netherlands

1969

(xi, 133 pages)

1 Energy --;1.1 The Realm of Thermodynamics --;1.2 Setting the Scene; Basic Ideas --;1.3 Forms of Energy and Their Interconversion --;2 The First Law Of Thermodynamics --;2.1 Statement of the First Law --;2.2 A New Function-Enthalpy --;2.3 Uses and Conventions of?H --;3 Thermochemistry --;3.1 Calorimetry --;3.2 Concepts of Heat Capacity --;3.3 Bond Energies --;4 Spontaneous Changes --;4.1 Everyday Processes --;4.2 Exothermicity, a Possible Criterion --;4.3 The Second Driving Force --;5 Entropy --;5.1 Measurement of Entropy --;5.2 Absolute Entropies --;5.3 The Direction of Time --;5.4 A Statistical Approach to Entropy --;6 Free Energy, The Arbiter --;6.1 Processes in Isolated Systems --;6.2 Gibbs Free Energy, G --;6.3 Gibbs Free Energy and Maximum Work --;6.4 Some Processes in Terms of Gibbs Free Energy --;6.5 Standard Free Energy Changes --;7 Chemical Equilibrium --;7.1 Preamble --;7.2 Variation of G with Gas Pressure --;7.3 The Active Mass of Pure Liquids and Solids --;7.4 Activity of Materials in Solution --;7.5 A Summing Up; Activity as a Unifying Concept --;7.6 Practical Aspects of Activity --;7.7 Equilibrium and the Reaction Isotherm --;8 Equilibrium Experiments and Their Interpretation --;8.1 The Reaction Isochore Equation --;8.2 Applications of the Isochore Equation --;8.3 The Clapeyron Equation --;9 Electrochemistry --;9.1 Electrochemical Cells --;9.2 Cell Energetics --;9.3 Standard Electrode Potentials --;9.4 Variation of Cell e.m.f. with Activity --;9.5 Variation of e.m.f. with Temperature --;10 Free Energy And Industrial Processes --;10.1 Free Energies as a Function of Temperature --;10.2 The Synthesis of Ethanol --;10.3 Ellingham Diagrams --;Suggested Further Reading --;Appendix I: The Twenty Most Useful Equations --;Appendix II: Fundamental Constants and Conversion Factors --;Answers to Problems.

Science (General)

by J.R.W. Warn.

J R W Warn

[Book]

Y