State-to-state dynamical research in the F+H2 reaction system
نام عام مواد
[Book]
نام نخستين پديدآور
/ Zefeng Ren
وضعیت نشر و پخش و غیره
محل نشرو پخش و غیره
Heidelberg
نام ناشر، پخش کننده و غيره
: Springer,
تاریخ نشرو بخش و غیره
, 2014.
فروست
عنوان فروست
(Springer theses)
یادداشتهای مربوط به نشر، بخش و غیره
متن يادداشت
Electronic
یادداشتهای مربوط به کتابنامه ، واژه نامه و نمایه های داخل اثر
متن يادداشت
Includes bibliographical references..
یادداشتهای مربوط به مندرجات
متن يادداشت
Summary: This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F@*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
متن يادداشت
Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2?DF+D.