Assembled lanthanide complexes with advanced photophysical properties /
نام عام مواد
[Book]
نام نخستين پديدآور
Yuichi Hirai.
وضعیت نشر و پخش و غیره
محل نشرو پخش و غیره
Singapore :
نام ناشر، پخش کننده و غيره
Springer,
تاریخ نشرو بخش و غیره
2018.
مشخصات ظاهری
نام خاص و کميت اثر
1 online resource (xv, 106 pages)
فروست
عنوان فروست
Springer theses,
شاپا ي ISSN فروست
2190-5053
يادداشت کلی
متن يادداشت
"Doctoral thesis accepted by the Hokkaido University, Hokkaido, Japan."
یادداشتهای مربوط به کتابنامه ، واژه نامه و نمایه های داخل اثر
متن يادداشت
Includes bibliographical references.
یادداشتهای مربوط به مندرجات
متن يادداشت
Intro; Supervisor's Foreword; Parts of this thesis have been published in the following journal articles:; Acknowledgements; Contents; 1 General Introduction; 1.1 Luminescent Materials; 1.2 Luminescence of Lanthanide(III) Ions; 1.3 Enhancement of Luminescence Efficiency; 1.3.1 The Antenna Effect; 1.3.2 Promotion of 4f-4f Transitions; 1.3.3 Suppression of Vibrational Relaxation; 1.4 Assembled Structures of Coordination Compounds; 1.5 Assembled Ln(III) Coordination Compounds; 1.6 Objectives; 1.7 Contents of This Thesis; References.
متن يادداشت
2 Luminescent Lanthanide Coordination Zippers with Dense-Packed Structures for High Energy Transfer Efficiencies2.1 Introduction; 2.2 Experimental Section; 2.2.1 General; 2.2.2 Apparatus; 2.2.3 Syntheses; 2.2.4 Crystallography; 2.2.5 Assignment of Coordination Geometry; 2.2.6 Optical Measurements; 2.2.7 Estimation of Intrinsic Emission Quantum Yields; 2.3 Results and Discussion; 2.3.1 Photophysical Properties; 2.3.2 Coordination Structures; 2.3.3 Thermal Properties; 2.3.4 DFT Calculations; 2.4 Conclusions; References.
This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers' fundamental understanding of solid-state photophysics and materials chemistry. Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f-4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.
یادداشتهای مربوط به سفارشات
منبع سفارش / آدرس اشتراک
Springer Nature
شماره انبار
com.springer.onix.9789811089329
ویراست دیگر از اثر در قالب دیگر رسانه
عنوان
Assembled lanthanide complexes with advanced photophysical properties.
شماره استاندارد بين المللي کتاب و موسيقي
9789811089312
موضوع (اسم عام یاعبارت اسمی عام)
موضوع مستند نشده
Phosphors.
موضوع مستند نشده
Rare earth metals.
موضوع مستند نشده
Phosphors.
موضوع مستند نشده
Rare earth metals.
موضوع مستند نشده
SCIENCE-- Chemistry-- Inorganic.
مقوله موضوعی
موضوع مستند نشده
PNND
موضوع مستند نشده
SCI-- 013030
رده بندی ديویی
شماره
546/
.
41
ويراست
23
رده بندی کنگره
شماره رده
QD172
.
R2
نام شخص به منزله سر شناسه - (مسئولیت معنوی درجه اول )