عنوان

Gyroid optical metamaterials :

شابک

3030030113

شابک

9783030030117

شابک اشتباه

3030030105

شابک اشتباه

9783030030100

عنوان اصلي

Gyroid optical metamaterials :

نام عام مواد

[Book]

ساير اطلاعات عنواني

solvent vapour annealing, confined crystallisation, and optical anisotropy /

نام نخستين پديدآور

James A. Dolan.

محل نشرو پخش و غیره

Cham, Switzerland :

نام ناشر، پخش کننده و غيره

Springer,

تاریخ نشرو بخش و غیره

2018.

نام خاص و کميت اثر

1 online resource (xxii, 132 pages) :

ساير جزييات

illustrations (some color)

عنوان فروست

Springer theses,

شاپا ي ISSN فروست

2190-5053

متن يادداشت

"Doctoral thesis accepted by the University of Cambridge, Cambridge, UK."

متن يادداشت

Includes bibliographical references.

متن يادداشت

Intro; Supervisor's Foreword; Abstract; Acknowledgements; Contents; 1 Preamble; References; 2 Introduction; 2.1 Gyroids; 2.1.1 Level Surfaces; 2.1.2 Gyroid Surface; 2.1.3 Single Gyroid; 2.1.4 Double Gyroid; 2.2 Block Copolymer Self-assembly; 2.2.1 Diblock Copolymers; 2.2.2 Triblock Terpolymers; 2.3 Solvent Vapour Annealing; 2.3.1 Diblock Copolymers; 2.3.2 Triblock Copolymers and Terpolymers; 2.3.3 Gyroid-Forming Block Copolymers; 2.4 Block Copolymer Crystallisation; 2.4.1 Spherulites; 2.4.2 Crystallisation Temperature; 2.4.3 Gyroid-Forming Block Copolymers; 2.5 Metamaterials

متن يادداشت

2.6 Gyroid Optical Metamaterials2.6.1 Fabrication; 2.6.2 Optical Properties; 2.6.3 Simulations and Theoretical Description; References; 3 Methods; 3.1 Terpolymer Thin Films; 3.2 Differential Scanning Calorimetry; 3.3 Annealing; 3.3.1 Thermal Annealing; 3.3.2 In Situ Solvent Vapour Annealing; 3.3.3 Ex Situ Solvent Vapour Annealing; 3.4 Film Thickness Measurements; 3.5 Grazing-Incidence Small- and Wide-Angle X-Ray Scattering; 3.5.1 Paul Scherrer Institute; 3.5.2 Cornell High Energy Synchrotron Source; 3.5.3 Data Analysis; 3.6 Electrodeposition of Gold; 3.7 Optical Characterisation

متن يادداشت

3.7.1 Optical Microscopy3.7.2 Reflection Goniometry; 3.7.3 Transmission Goniometry; 3.8 Optical Simulations; References; Part I Solvent Vapour Annealing of a Gyroid-Forming Triblock Terpolymer; 4 In Situ GISAXS During Solvent Vapour Annealing of a Gyroid-Forming ISO Triblock Terpolymer; 4.1 Methods; 4.2 Results; 4.2.1 Solvent Vapour Annealing (SVA) Regimes; 4.2.2 Effect of Maximum Swelling Ratio and Solvent Removal Rate; 4.2.3 Effect of Different Solvent and Mixed Solvent Vapours; 4.3 Discussion; 4.3.1 Alternating Gyroid Morphology; 4.3.2 Robust Morphology and Flexible Unit Cell Size

متن يادداشت

4.4 ConclusionReferences; 5 Preferentially Aligned Crystallisation Within a Single Gyroid Network of an ISO Triblock Terpolymer; 5.1 Methods; 5.2 Results; 5.2.1 Crystalline Superstructure; 5.2.2 Microphase-Separated Morphology; 5.2.3 Correlation of Crystalline Superstructure with Microphase-Separated Morphology; 5.3 Discussion; 5.3.1 Confined Crystallisation; 5.3.2 Multiple Individually Aligned Crystallites; 5.3.3 Crystallite Orientation; 5.3.4 Preferentially Aligned Crystallisation Along the langle111 rangle and langle100 rangle Directions

متن يادداشت

5.3.5 Distribution of Local Crystallite Orientations5.4 Conclusion; References; Part II Optical Anisotropy in Gyroid Optical Metamaterials; 6 Multi-Domain Gyroid Optical Metamaterials; 6.1 Methods; 6.2 Effective Medium Theories; 6.2.1 Maxwell-Garnett Theory: Spherical Inclusions; 6.2.2 Bruggeman Theory: Spherical Inclusions; 6.2.3 Bruggeman Theory: Ellipsoidal Inclusions; 6.2.4 Model Fitting; 6.3 Results; 6.3.1 Multi-Domain Gyroid Optical Metamaterials; 6.3.2 Effective Medium Models; 6.3.3 Host Refractive Index and Volume Fill Fraction; 6.4 Discussion; 6.4.1 Bruggeman Random Wire Array

بدون عنوان

0

بدون عنوان

8

بدون عنوان

8

بدون عنوان

8

بدون عنوان

8

متن يادداشت

This thesis explores the fabrication of gyroid-forming block copolymer templates and the optical properties of the resulting gyroid optical metamaterials, significantly contributing to our understanding of both. It demonstrates solvent vapour annealing to improve the long-range order of the templates, and investigates the unique crystallisation behaviour of their semicrystalline block. Furthermore, it shows that gyroid optical metamaterials that exhibit only short-range order are optically equivalent to nanoporous gold, and that the anomalous linear dichroism of gyroid optical metamaterials with long-range order is the result of the surface termination of the bulk gyroid morphology. Optical metamaterials are artificially engineered materials that, by virtue of their structure rather than their chemistry, may exhibit various optical properties not otherwise encountered in nature (e.g. a negative refractive index). However, these structures must be significantly smaller than the wavelength of visible light and are therefore challenging to fabricate using traditional "top down" techniques. Instead, a "bottom up" approach can be used, whereby optical metamaterials are fabricated via templates created by the self-assembly of block-copolymers. One such morphology is the gyroid, a chiral, continuous and triply periodic cubic network found in a range of natural and synthetic self-assembled systems.

منبع سفارش / آدرس اشتراک

Springer Nature

شماره انبار

com.springer.onix.9783030030117

عنوان

Gyroid optical metamaterials.

شماره استاندارد بين المللي کتاب و موسيقي

9783030030100

موضوع مستند نشده

Copolymers.

موضوع مستند نشده

Metamaterials.

موضوع مستند نشده

Condensed matter physics (liquid state & solid state physics)

موضوع مستند نشده

Copolymers.

موضوع مستند نشده

Metamaterials.

موضوع مستند نشده

Nanotechnology.

موضوع مستند نشده

TECHNOLOGY & ENGINEERING-- Engineering (General)

موضوع مستند نشده

TECHNOLOGY & ENGINEERING-- Reference.

موضوع مستند نشده

PHFC

موضوع مستند نشده

PHFC

موضوع مستند نشده

TEC-- 009000

موضوع مستند نشده

TEC-- 035000

شماره

ويراست

شماره رده

مستند نام اشخاص تاييد نشده

Dolan, James A.

تاريخ عمليات

20200823074848.0

قواعد فهرست نويسي ( بخش توصيفي )

pn

نام الکترونيکي

نوع ماده

[Book]

تكميل شده

Y