State-to-state dynamical research in the F+H2 reaction system / monograph.
نام عام مواد
[Book]
نام نخستين پديدآور
Zefeng Ren.
وضعیت نشر و پخش و غیره
محل نشرو پخش و غیره
Berlin
نام ناشر، پخش کننده و غيره
Springer
تاریخ نشرو بخش و غیره
2014
مشخصات ظاهری
نام خاص و کميت اثر
xii, 77 pages : illustrations (some color) ; 24 cm.
فروست
عنوان فروست
Springer theses.
یادداشتهای مربوط به مندرجات
متن يادداشت
Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus --; Dynamical Resonances in F+H2 Reactions --; The Non-Adiabatic Effects in F(2P)+D2?DF+D.
یادداشتهای مربوط به خلاصه یا چکیده
متن يادداشت
This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
موضوع (اسم عام یاعبارت اسمی عام)
موضوع مستند نشده
Chemical reactions.
موضوع مستند نشده
Hydrogen.
موضوع مستند نشده
Rydberg states.
رده بندی کنگره
شماره رده
QD501
نشانه اثر
.
Z444
2014
نام شخص به منزله سر شناسه - (مسئولیت معنوی درجه اول )