Machine derived contents note: Preface ix -- Chapter 1 Radiation Curing 1 -- Introduction 1 -- What is Radiation Curing and Why is it Used? 3 -- Radiation 6 -- Simplified Classic to Modem Light/Radiation/Energy Theory 8 -- Magnitude of Ultraviolet and Visible Radiation Energy 10 -- Photon Production 12 -- Electrons 12 -- References 13 -- Chapter 2 Curing Equipment 15 -- Electron Beams 17 -- Ultraviolet Radiation Systems 20 -- Xenon Lamps 26 -- Hybrid Xenon/Mercury Lamps 28 -- Excimer Radiation 29 -- Visible Radiation, Light 29 -- References 30 -- Chapter 3 Free-Radical Photoinitiators and Initiation Mechanism 35 -- Introduction 35 -- Photoinitiators 37 -- Free Radical Photoinitiators 37 -- Homolytic Fragmentation Type 38 -- Hydrogen Abstraction Type 41 -- Photosensitizers 44 -- Oxygen Inhibition 45 -- Visible Radiation Photoinitiators 48 -- References 50 -- Chapter 4 Cationic Photoinitiators and Initiation Mechanism 55 -- Introduction 55 -- Onium Salts, General 55 -- Diazonium Salts, Lewis Acids 56 -- Iodonium and Sulfonium Salts, Bronsted Acids 59 -- Organometallic Compounds 64 -- Photosensitization 66 -- References 67 -- Chapter 5 Free Radical Initiated Polymerization Systems 73 -- Free Radical Systems 73 -- Unsaturated Polyester/Styrene Systems 74 -- Polyene/Thiol Compositions 77 -- Acrylate Compositions 81 -- Monofunctional Acrylates 83 -- Polyfunctional Acrylates 87 -- Oligomeric Acrylates-Epoxy, Urethane, Oils 88 -- Acrylated Epoxides or Epoxy Acrylates 88 -- Urethane Acrylates 92 -- Esterified Polyol Acrylates 97 -- Acrylated Oils 98 -- Shrinkage 100 -- References 101 -- Chapter 6 Cationic Initiated Polymerization Systems 109 -- Cationic Cycloaliphatic Epoxide Systems 109 -- Oils 115 -- Mechanism of Polymerization 117 -- Polyols 118 -- Water, Humidity, and Temperature Effects 122 -- Effect of Added Thermal Energy 123 -- Electron Beams and Epoxide Cure 123 -- Pigmentation 124 -- Formulation 125 -- References 125 -- Chapter 7 Vinyl Ethers 129 -- Introduction 129 -- Free Radical Polymerization 130 -- Cationic Polymerization 132 -- Hybrid Polymerizations 134 -- Donor/Acceptor or Charge-Transfer Polymerizations 135 -- Oligomeric Vinyl Ethers 138 -- Urethane Vinyl Ethers 138 -- Ester Vinyl Ethers 139 -- Vinyl Ether-Silicone Blends 140 -- Vinyl Ether-Epoxide Blends 141 -- References 142 -- Chapter 8 Ultraviolet Radiation-Curable Powder Coatings 145 -- Introduction 145 -- Polymer Systems 148 -- Wood Substrates 149 -- Metal Substrates 150 -- Fiberboard Substrates 151 -- Summary 151 -- References 152 -- Chapter 9 Dual-Cure Mechanisms 155 -- Free Radical/Cationic Systems 155 -- Radiation/Thermal Cures 156 -- Radiation/Moisture-Cure Urethane Cures 160 -- Radiation/Epoxide Cure 161 -- Radiation/Radiation Cure 162 -- Radiation/Air-Drying Cures 162 -- References 163 -- Chapter 10 Adhesives 165 -- Introduction 165 -- Pressure Sensitive Adhesives 166 -- Release or Anti-Adhesive Coatings 172 -- Other Adhesives 176 -- References 178 -- Chapter 11 Additives and Miscellaneous 183 -- Antifoaming Agents 183 -- Expanding Monomers 183 -- Gloss Control 185 -- Inorganic Glasses for Pigmented and Thick Section Cures 186 -- Odor 186 -- Scratch, Slip, and Abrasion Resistance 188 -- Silane Coupling Agents 190 -- Surfactants 192 -- Textured Coatings 194 -- Thick Section Curing 195 -- Water-Based Systems 195 -- Weathering 196 -- References 198 -- Chapter 12 Safety and Health Considerations 203 -- References 207 -- Chapter 13 End Uses 211 -- Automotive 211 -- Electrical/Electronics 212 -- Magnetic Media 213 -- Optical Components and Materials 215 -- Printing Inks and Graphic Arts 216 -- Stereolithography or Three-Dimensional Object Curing 216 -- Wood Coatings 218 -- General 220 -- The Future 220 -- References 222 -- Glossary of Terms 233 -- Index 239.
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SUMMARY OR ABSTRACT
Text of Note
The technology that deals with using the substrate as your polymerization vessel will be described in detail, but in an understandable manner, in this book. Reading it will give one a good understanding of this topic and enough knowledge to begin formulating radiation-curable inks, coatings, and sealants.
TOPICAL NAME USED AS SUBJECT
Plastic coating.
Radiation curing.
Radiation-- Industrial applications.
Ultraviolet radiation-- Industrial applications.
Plastic coating.
Radiation curing.
Radiation-- Industrial applications.
Ultraviolet radiation-- Industrial applications.
DEWEY DECIMAL CLASSIFICATION
Number
668
.
4
Edition
21
LIBRARY OF CONGRESS CLASSIFICATION
Class number
TP156
.
C8
Book number
K66
2002
PERSONAL NAME - PRIMARY RESPONSIBILITY
Koleske, J. V.,1930-
CORPORATE BODY NAME - ALTERNATIVE RESPONSIBILITY
ASTM Committee D-1 on Paint and Related Coatings, Materials, and Applications.