Front Cover; Organomagnesium Methods in Organic Synthesis; Copyright Page; Contents; Foreword; Preface; Detailed Contents; Abbreviations; Chapter 1. Introduction and General References; Chapter 2. General Considerations in the Application of Organomagnesium Compounds in Organic and Organometallic Synthesis; Chapter 3. Preparation of Organomagnesium Compounds; Chapter 4. Addition of Organomagnesium Compounds to Carbon-Carbon Multiple Bonds; Chapter 5. Addition of Organomagnesium Compounds to Carbon-Nitrogen Multiple Bonds; Chapter 6. Addition of Organomagnesium Compounds to Carbonyl Groups
Text of Note
Chapter 14. Formation of Carbon-Halogen Bonds via Organomagnesium CompoundsChapter 15. Synthesis of Organoboron, Organosilicon and Organophosphorus Compounds from Organomagnesium Compounds; Chapter 16. Organomagnesium Compounds in the Synihesis of Other Organometallic Compounds; Index of Compounds and Methods
Text of Note
Chapter 7. Carbophilic Addition of Organomagnesium Compounds to Thiocarbonyl GroupsChapter 8. Substitution at Carbon by Organomagnesium Compounds; Chapter 9. Carbenoid and Arynoid Reactions of Organomagnesium Compounds; Chapter 10. Reactions of Organomagnesium Compounds with Proton Donors; Chapter 11. Formation of Carbon-Nitrogen Bonds via Organomagnesium Compounds; Chapter 12. Formation of Carbon-Oxygen Bonds via Organomagnesium Compounds; Chapter 13. Formation of Carbon-Sulfur, Carbon-Selenium and Carbon-Tellurium Bonds via Organomagnesium Compounds
0
8
8
SUMMARY OR ABSTRACT
Text of Note
The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized.The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as.