عنوان

Organometallics for green catalysis /

(Number (ISBN

3030109550

(Number (ISBN

9783030109554

Erroneous ISBN

3030109542

Erroneous ISBN

3030109569

Erroneous ISBN

9783030109547

Erroneous ISBN

9783030109561

Title Proper

Organometallics for green catalysis /

General Material Designation

[Book]

First Statement of Responsibility

Pierre H. Dixneuf, Jean-François Soulé, editors.

Place of Publication, Distribution, etc.

Cham :

Name of Publisher, Distributor, etc.

Springer,

Date of Publication, Distribution, etc.

[2019]

Specific Material Designation and Extent of Item

1 online resource

Series Title

Topics in organometallic chemistry ;

Volume Designation

63

Text of Note

Includes index.

Text of Note

Metal-Catalysed Hydrogenation of CO2 into Methanol -- Catalytic C-C Bond Formations from CO2 with Alkenes -- Recent advances on CO2 utilization as C1 building block in C-N and C-O bond formation -- â#x80;Alkene Metathesis for Transformation of Renewablesâ#x80;#x9D; -- Metal-Catalyzed Aromatic C-O Bond Activation/Transformation -- Hydrogenation/Dehydrogenation of Unsaturated Bonds with Iron Pincer Catalysis -- Conversion of Alcohols to Carboxylates Using Water and Base with H2 Liberation -- Selective Transfer-hydrogenation of α, β-Unsaturated Carbonyl Compounds -- Functionalization of C(sp2)â#x80;#x93;H Bonds of Arenes and Heteroarenes Assisted by Photoredox-Catalysts for the Câ#x80;#x93;C Bond Formation -- Green Cross-Coupling using Visible-light for C-O and C-N Bond Formation.

0

Text of Note

This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol an eco-friendly energy storage strategy and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and CO bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective CH bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. CH bond oxidation using visible light leads mainly to the formation of CO and CN bonds, whereas cross-coupled CC bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.

Source for Acquisition/Subscription Address

Springer Nature

Stock Number

com.springer.onix.9783030109554

International Standard Book Number

9783030109547

Green chemistry.

Organometallic compounds.

Catalysis.

Green Chemistry.

Industrial Chemistry/Chemical Engineering.

Organometallic Chemistry.

Green chemistry.

Organometallic compounds.

PNRD

PNRD

SCI013060

Number

Edition

Class number

Book number

Dixneuf, P. H., (Pierre H.)

Soulé, Jean-François.

Date of Transaction

20200823082630.0

Cataloguing Rules (Descriptive Conventions))

pn

Electronic name

[Book]

Y