عنوان

Multidimensional time-resolved spectroscopy /

3030024784

9783030024789

3030024776

9783030024772

Multidimensional time-resolved spectroscopy /

[Book]

Tiago Buckup, Jérémie Léonard, editors ; with contributions from Johanna Brazard, Tiago Buckup, Thomas P. Cheshire, Marco Garavelli, Zhenkun Guo, Harold Y. Hwang, Jan Philip Kraak, Jérémie Léonard, Xian Li, Jian Lu, Margherita Maiuri, Brian P. Molesky, Andrew M. Moran, Shaul Mukamel, Keith A. Nelson, Artur Nenov, Benjamin K. Ofori-Okai, Ivan Rivalta, Javier Segarra-Martí, Yaquing Zhang.

Cham :

Springer,

[2019]

1 online resource (ix, 320 pages :

colour illustrations

Topics in current chemistry collections,

2367-4067

Includes bibliographical references.

Intro; Contents; Preface; Introduction to State-of-the-Art Multidimensional Time-Resolved Spectroscopy Methods; Abstract; 1 Introduction; 2 Classification of Multidimensional Techniques; 3 2D Plots; 4 Experimental Aspects of Multidimensional Time-Resolved Spectroscopy; 5 What Can a Chemist Learn from Multidimensional Time-Resolved Spectroscopy?; 6 How is this Collection Organized; 7 Conclusions and Outlook; 8 Further Reading; References; Electronic Couplings in (Bio- ) Chemical Processes; Abstract; 1 Introduction; 2 Implementation; 3 Heterogeneity; 4 Excitation Energy Transfer (EET)

2.1 Molecular Information from Diagonal and Off-Diagonal Peaks in 2D IR Spectra2.1.1 Diagonal Peaks; 2.1.2 Off-Diagonal Peaks; 3 Applications of 2D IR Spectroscopy for Molecular Structure Determination; 3.1 2D IR for Chemistry and Biology; 3.1.1 3D Molecular Structure from Vibrational Couplings in 2D IR Spectra; 3.1.2 Bio-Molecular Structure from Quasi-Static 2D IR Spectra; 3.1.3 Structural Dynamics Resolved from Spectral Diffusion in 2D IR Spectroscopy; 3.1.4 Structural Dynamics Resolved with 2D IR Chemical Exchange Spectroscopy

3.1.5 Intermolecular and Intramolecular Vibrational Energy Transfer Observed with 2D IR3.1.5.1 Intermolecular Energy Transfer; 3.1.5.2 Intramolecular Energy Transfer; 3.2 Structural Dynamics of Molecules in Confined Environments; 3.2.1 2D IR from Molecules Confined in Two Dimensions: Surfaces and Interfaces; 3.2.2 2D IR Spectroscopy of Three-Dimensionally Confined Molecules; 4 Extensions of 2D IR Spectroscopy; 4.2 2D IR Microscopy; 4.3 3D IR Spectroscopy; 4.4 Transient 2D IR Spectroscopy; 4.4.1 Extending the Observation Window for 2D IR Spectroscopy

4.2 2DES for Tracking GS Conformational Dynamics4.3 Excited-State Coherent Vibrational Dynamics Resolved by 2DES; 4.4 Spectral Characterization of Long-Lived ES Intermediates; 5 Outlook and Perspectives; Acknowledegements; References; Ultrafast structural molecular dynamics investigated with 2D infrared spectroscopy methods; Abstract; 1 Introduction; 1.1 Ultrafast Infrared Vibrational Spectroscopy; 1.2 Multi-Dimensional IR Spectroscopy; 1.3 Scientific Impact of 2D IR Spectroscopy; 1.4 Scope of this Chapter; 2 Essential Elements of 2D IR Spectroscopy

5 Vibronic Coupling6 Photoreactivity; 7 Conclusions and Perspectives; 7.1 2DES-UV; 7.2 Incoherent 2DES; 7.3 2DES Stark; 7.4 Fluorescence 2DES; 7.5 2DES Photo-Current; References; Towards Accurate Simulation of Two-Dimensional Electronic Spectroscopy; Abstract; 1 Introduction; 2 The 2DES Technique; 2.1 2DES in the Ultraviolet: A New Light in Photobiology; 3 Theoretical Background; 3.1 Density Matrix Formalism and 2DES Response Functions; 3.2 Coupling Accurate Electronic Structure Computations to 2DES; 4 Results and Discussion; 4.1 Benchmarking the Excited-State Manifolds

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The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Multidimensional time-resolved spectroscopy.

9783030024772

Spectrum analysis.

Time-resolved spectroscopy.

Spectrum analysis.

Time-resolved spectroscopy.

PNFS

PNFS

SCI078000

Buckup, Tiago,1976-

Léonard, Jérémie,1975-

20200823074241.0

pn

[Book]

Y