عنوان

Alkyne-based nanostructures on silver substrates /

(Number (ISBN

3030009971

(Number (ISBN

9783030009977

Erroneous ISBN

3030009963

Erroneous ISBN

9783030009960

Title Proper

Alkyne-based nanostructures on silver substrates /

General Material Designation

[Book]

First Statement of Responsibility

Raphael Hellwig.

Place of Publication, Distribution, etc.

Cham, Switzerland :

Name of Publisher, Distributor, etc.

Springer,

Date of Publication, Distribution, etc.

2018.

Specific Material Designation and Extent of Item

1 online resource (xv, 119 pages) :

Other Physical Details

illustrations (some color)

Series Title

Springer theses,

ISSN of Series

2190-5053

Text of Note

"Doctoral thesis accepted by the TU München, Garching, Germany."

Text of Note

Includes bibliographical references.

Text of Note

Introduction -- Experimental methods -- Silver-bis-acetylide wires -- Fabrication of graphdiyne nanowires -- Metal alkynyl pi complexes -- Ho-catalyzed cyclotrimerization -- Conclusion and outlook.

0

Text of Note

Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the author establishes protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions.

Source for Acquisition/Subscription Address

Springer Nature

Stock Number

com.springer.onix.9783030009977

Title

Alkyne-based nanostructures on silver substrates.

International Standard Book Number

9783030009960

Nanostructured materials.

Nanoscale Science and Technology.

Organometallic Chemistry.

Surfaces and Interfaces, Thin Films.

Materials science.

Nanostructured materials.

Nanotechnology.

Organometallic chemistry.

TECHNOLOGY & ENGINEERING-- Engineering (General)

TECHNOLOGY & ENGINEERING-- Reference.

TBN

TBN

TEC-- 009000

TEC-- 035000

Number

Edition

Class number

Hellwig, Raphael

Date of Transaction

20200823072443.0

Cataloguing Rules (Descriptive Conventions))

pn

Electronic name

[Book]

Y