عنوان

Rubber Chemistry

(Number (ISBN

9400992211

(Number (ISBN

9400992238

(Number (ISBN

9789400992214

(Number (ISBN

9789400992238

Number

b594085

Title Proper

Rubber Chemistry

General Material Designation

[Book]

First Statement of Responsibility

by J.A. Brydson.

Place of Publication, Distribution, etc.

Dordrecht

Name of Publisher, Distributor, etc.

Springer Netherlands

Date of Publication, Distribution, etc.

1979

Specific Material Designation and Extent of Item

(458 pages)

Text of Note

1 The Historical Development of Rubber Chemistry.- 1.1. Introduction.- 1.2. Early Years.- 1.3. Synthetic Rubber.- 1.4. Hot and Cold War: Hot and Cold Rubber.- 1.5. Stereo and Speciality Rubbers.- 1.6. Reactivity of Rubbers.- 1.7. Future Trends.- 2 The Chemical Nature of the Natural Rubber Molecule.- 2.1. Introduction.- 2.2. The Chemical Formula of Natural Rubber.- 2.3. Molecular Weight and the Molecular Weight Distribution.- 2.4. Minor Groupings and Microgel.- 2.5. End-groups.- 2.6. The Protein Effect.- 3 The Molecular Nature of Rubber Elasticity.- 3.1. Introduction.- 3.2. Molecular Dimensions.- 3.3. Elasticity of a Single Chain.- 3.4. Elasticity of a Network.- 3.5. Non-Gaussian Networks.- 3.6. Alternative Relationships.- 3.7. Thermodynamic Aspects.- 3.8. Conclusions.- 4 Structure-Property Relationships in Rubbers.- 4.1. Basic Considerations.- 4.2. Non-rubbery Properties.- 4.3. Structure and Processing Properties.- 4.4. Strength of Rubbers.- 5 Diene Homopolymer Rubbers.- 5.1. Introduction.- 5.2. Preparation of Monomers.- 5.3. Isomerism in Diene Rubbers.- 5.4. Characterization of Microstructure.- 5.5. Polymerization of Dienes.- 5.6. Structure and Properties of Diene Rubbers.- 6 Diene-Based Copolymers.- 6.1. Introduction.- 6.2. Copolymer Structure-General Considerations.- 6.3. Styrene-Butadiene Rubber.- 6.4. Nitrile Rubbers.- 6.5. Vinyl Pyridine Rubbers.- 6.6. Butadiene-Methyl Isopropenyl Ketone Rubbers.- 6.7. Alternating Olefin-Diolefin Copolymers.- 7 Reactivity of Diene Rubbers-I.- 7.1. General Considerations.- 7.2. Reactivity of Alkenes.- 7.3. Hydrogenation.- 7.4. Hydrohalogenation.- 7.5. Halogenation.- 7.6. Cis-Trans-Isomerization.- 7.7. Cyclized Rubber.- 7.8. Maleic Derivatives.- 7.9. Epoxidized, Hydroxy-esterified and Hydroxy-halogenated Diene Polymers.- 7.10. 'Ene' and 1, 3-Dipolar Reactions.- 7.11. Conclusions.- 8 Reactivity of Diene Rubbers-II: Cross-Linking Processes.- 8.1. Introduction.- 8.2. Accelerated Sulphur Vulcanization.- 8.3. Vulcanization by Sulphur-containing Compounds.- 8.4. Vulcanization without Sulphur or Sulphur Compounds.- 9 Reactivity of Diene Rubbers-III: Oxidation And Related Processes.- 9.1. Introduction.- 9.2. Oxidation of Saturated and Unsaturated Hydrocarbons.- 9.3. Oxidation of Sulphides and Olefin-Sulphide Systems.- 9.4. Oxidation of Diene Rubber Network Structures.- 9.5. Protection against Oxidation.- 9.6. Mastication, Oxidation and Mechanochemistry.- 9.7. Reaction of Ozone with Diene Rubbers.- 10 Polychloroprene.- 10.1. Introduction.- 10.2. Monomer Preparation and Properties.- 10.3. Polymerization.- 10.4. Polymer Structure.- 10.5. Vulcanization.- 10.6. Oxidation and Ageing.- 10.7. Technological Comparison of Polychloroprenes.- 11 Polyisobutene and Butyl Rubber.- 11.1. Introduction.- 11.2. Polymerization Chemistry and Manufacture.- 11.3. Structure of Polyisobutene and Butyl Rubber.- 11.4. Halogenation of Butyl Rubber.- 11.5. Identification and Characterization.- 11.6. Cross-linking of Butyl.- 11.7. Miscellaneous Butyl-type Rubbers.- 12 Rubbers Based on Ethylene.- 12.1. Introduction.- 12.2. Ethylene-Propylene Rubbers.- 12.3. Rubbery Copolymers of Ethylene with Polar Monomers.- 12.4. Chlorinated and Chlorosulphonated Polymers.- 13 Fluorine-Containing Rubbers.- 13.1. Introduction.- 13.2. Early Developments.- 13.3. Copolymers Containing Vinylidene Fluoride.- 13.4. Copolymers Containing Perfluoro (Methyl Vinyl Ether).- 13.5. Nitroso-fluoroelastomers.- 13.6. Phosphonitrile Fluoroelastomers.- 13.7. Perfluoroalkylenetriazine Elastomers.- 13.8. Poly(Thiocarbonyl Fluoride) and Related Elastomers.- 13.9. Miscellaneous Fluoroelastomers.- 14 Acrylic Rubbers.- 14.1. Introduction.- 14.2. General Polymerization Chemistry of Acrylic Rubbers.- 14.3. The Development of Oil-resistant Rubbers with Low Brittle Point.- 14.4. Reactive Cure Sites.- 14.5. Curing Systems.- 14.6. Ageing of Acrylic Rubbers.- 14.7. Polyvinyl Ether Elastomers.- 15 Rubbers Produced by Condensation and Ring Opening Polymerization Mechanisms.- 15.1. Introduction.- 15.2. Polyesters and Polyester-amides.- 15.3. Polyamides.- 15.4. Polyethers and Polythioethers.- 15.5. Polysulphides.- 15.6. The Silicones.- 15.7. Polyalkenamers.- 15.8. Polynorbornene.- 16 Polyurethane Rubbers.- 16.1. Introduction.- 16.2. Intermediates, Structure and Properties.- 16.3. Cross-linking and Physical Properties.- 16.4. Cast Polyurethane Rubbers.- 16.5. Millable Gums.- 16.6. Cellular Polyurethanes.- 16.7. Thermoplastic Polyurethanes.- 16.8. Toxicity Hazards in Polyurethane Technology.- 17 Thermoplastic Rubbers.- 17.1 Introduction.- 17.2. Block Copolymers.- 17.3. Survey of Industrial Block Copolymer Thermoplastic Rubbers.

Polymers.

Surfaces (Physics)

Class number

Book number

by J.A. Brydson.

J A Brydson

Electronic name

[Book]

Y