عنوان

The Chemistry of Linear Oligopyrroles and Bile Pigments

(Number (ISBN

3709169380

(Number (ISBN

9783709169384

Number

b587279

Title Proper

The Chemistry of Linear Oligopyrroles and Bile Pigments

General Material Designation

[Book]

First Statement of Responsibility

by Heinz Falk.

Place of Publication, Distribution, etc.

Vienna

Name of Publisher, Distributor, etc.

Springer Vienna

Date of Publication, Distribution, etc.

1989

Specific Material Designation and Extent of Item

(xi, 621 pages 344 illustrations)

Series Title

Monatshefte für Chemie/Chemical Monthly Supplementa, 1.

Text of Note

1. Introduction.- 2. Nomenclature.- 3. Occurrence, Formation, and Importance.- 4. Historical Aspects.- 5. Structure and Stereochemistry.- 5.1. General Considerations.- 5.1.1. Definitions.- Constitution.- Tautomerism.- Configuration.- Conformation.- Association.- 5.1.2. Energetics, Interconversions, Interdependencies.- 5.1.3. Methods of Structural Analysis.- Crystalline Materials.- Amorphous Materials.- Solutions.- 5.1.4. Principal Considerations on Structural Aspects of Linear Oligopyrroles.- Bipyrroles.- Bipyrrolylidenes.- Dipyrrins (Pyrromethenes).- Dipyrrinones (Pyrromethenones).- 5,10-Dihydrodipyrrins (Dipyrrylmethanes).- Dihydrodipyrrinones (Dihydropyrromethenones).- Tetrahydrodipyrrinones (Tetrahydropyrromethenones).- Prodigiosenes.- Tripyrrinones.- 1,19-Dioxobilins.- Dihydrobilins: 1,19-Dioxobiladienes-ac.- Dihydrobilins: 1,19-Dioxobiladienes-ab.- Dihydrobilins:1,19-Dioxo-2,3-dihydrobilins.- Tetrahydrobilins: 1,19-Dioxobilenes-b.- Tetrahydrobilins: 1,19-Dioxo-2,3-dihydrobiladienes-ab.- Hexahydrobilins: 1,19-Dioxobilanes.- Hexahydrobilins: Bilanes.- Secocorrins.- 1,19-Dioxo-10-nor-bilins and 1,19-Dioxo-10-nor-biladienes-ac.- Pentapyrrins.- 5.2. Structural Aspects of Linear Dipyrroles.- 5.2.1. Bipyrroles, Bipyrrolylidenes, and Analoga.- 5.2.2. Dipyrrins (Pyrromethenes).- 5.2.3. Dipyrrinones (Pyrromethenones) and Analoga.- 5.2.4. 5,10-Dihydrodipyrrins (Dipyrrylmethanes).- 5.2.5. Dihydrodipyrrinones (Dihydropyrromethenones).- 5.2.6. Tetrahydrodipyrrinones (Tetrahydropyrromethenones).- 5.3. Structural Aspects of Linear Tripyrroles.- 5.3.1. Terpyrroles.- 5.3.2. Prodigiosenes.- 5.3.3. Tripyrrinones and Analoga.- 5.4. Structural Aspects of Linear Tetrapyrroles.- 5.4.1. 1,19-Dioxobilins and Bilins.- 5.4.2. Dihydrobilins: 1,19-Dioxo-2,3-dihydrobilins.- 5.4.3. Dihydrobilins: 1,19-Dioxobiladienes-ac.- 5.4.4. Dihydrobilins: 1,19-Dioxobiladienes-ab.- 5.4.5. Tetrahydrobilins: 1,19-Dioxo-2,3-dihydrobiladienes-ab.- 5.4.6. Tetrahydrobilins: 1,19-Dioxobilenes-b.- 5.4.7. Tetrahydrobilins: Secocorphins.- 5.4.8. Hexa- and Octahydrobilins.- 5.4.9. Secocorrins.- 5.4.10. 1,19-Dioxo-l0-nor- Bilins and Biladienes-ac.- 5.5. Structural Aspects of Linear Oligopyrroles Containing Five or More Rings.- 5.5.1. Pentapyrrins.- 5.5.2. Hexapyrrins and Higher Homologues.- 5.5.3. Polypyrrole.- 6. Synthesis.- 6.1. Principal Considerations.- 6.2. Synthesis of Linear Dipyrroles.- 6.2.1. Bipyrroles, Bipyrrolylidenes, and Analoga.- 6.2.2. Dipyrrins (Pyrromethenes) and Analoga.- 6.2.3. Dipyrrinones (Pyrromethenones) and Analoga.- 6.2.4. 5,10-Dihydrodipyrrins (Dipyrrylmethanes).- 6.2.5. Dihydrodipyrrinones (Dihydropyrromethenones).- 6.2.6. Tetrahydrodipyrrinones (Tetrahydropyrromethenones).- 6.2.7. Miscellaneous Dipyrroles.- 6.3. Synthesis of Linear Tripyrroles.- 6.4. Synthesis of Linear Tetrapyrroles.- 6.4.1. 1,19-Dioxobilins and Bilins.- 6.4.2. Dihydrobilins: 1,19-Dioxo-2,3-dihydrobilins.- 6.4.3. Dihydrobilins: 1,19-Dioxobiladienes-ac.- 6.4.4. Dihydrobilins: 1,19-Dioxobiladienes-ab.- 6.4.5. Tetrahydrobilins: 1,19-Dioxo-2,3-dihydrobiladienes-ab.- 6.4.6. Tetrahydrobilins: 1,19-Dioxobilenes-b.- 6.4.7. Tetrahydrobilins: Secocorphins.- 6.4.8. Hexahydrobilins and Octahydrobilins.- 6.4.9. Secocorrins.- 6.4.10. 1,19-Dioxo-l0-nor- Bilins and Biladienes-ac.- 6.5. Synthesis of Linear Pentapyrroles and Higher Homologues.- 6.6. Transformations of Functional Groups Attached to Linear Oligopyrroles.- 7. Selected Physical Properties.- 7.1. Crystallization, Melting, Solubility.- 7.2. Light Absorption.- 7.3. Chiroptical Properties.- 7.4. Light Emission.- 7.5. Vibrational Spectroscopy.- 7.6. Nuclear Magnetic Resonance.- 7.7. Mass Spectra.- 8. Reactions.- 8.1. Photochemistry.- 8.2. Protonation - Deprotonation.- 8.3. Coordination (Carrier Mediated Transport).- 8.4. Nucleophilic, Electrophilic, and Radical Reactivity of Linear Oligopyrroles.- 8.5. Substitution Reactions.- 8.6. Addition Reactions.- 8.7. Skeletal Transformations.- 8.8. Reduction - Oxidation.- 8.9. Linear Oligopyrroles as Catalysts.- References.- Author Index.

Chemistry, Organic.

Chemistry.

Physical organic chemistry.

by Heinz Falk.

Heinz Falk

Electronic name

[Book]

Y