Preface IX 1 Discovery, Invention, and Science in Human Progress 1 1.1 Origins of Technology, the Need for Human Survival 1 1.2 The Industrial Revolution: Watt s Steam Engine, Thermodynamics, Energy Sources 2 1.3 A Short History of Time: Navigation, Longitudes, Clocks 4 1.4 The Information Revolution: Abacus to Computer Chips and Fiber Optics 5 1.5 Overlap and Accelerating Cascade of Technologies: GPS, Nuclear Submarines 6 1.6 Silicon and Biotechnologies: Carbon Dating, Artificial Intelligence 7 1.7 Nanotechnology: A Leading Edge of Technological Advance, a Bridge to the Future 13 1.8 How to Use This Book 15 References 16 2 Smaller Is More, Usually Better, and Sometimes Entirely New! 17 2.1 Nanometers, Micrometers, Millimeters Visualizing a Nanometer 18 2.2 Moore s Law: from 30 Transistors to a Billion Transistors on One Chip and Cloud Computing 19 2.3 Miniaturization: Esaki s Tunneling Diode, 1-TB Magnetic Disk Read Heads 22 2.4 Accelerometers and Semiconductor Lasers 24 2.5 Nanophysics-Based Technology: Medical Imaging, Atomic Clock, Sensors, Quantum Computers 26 References 27 3 Systematics of Scaling Things Down: L = 1 m 1 nm 29 3.1 One-Dimensional and Three-Dimensional Scaling 29 3.2 Examples of Scaling: Clocks, Tuning Forks, Quartz Watches, Carbon Nanotubes 31 3.3 Scaling Relations Illustrated by Simple Circuit Elements 37 3.4 Viscous Forces for Small Particles in Fluid Media 38 3.5 What about Scaling Airplanes and Birds to Small Sizes? 39 References 40 4 Biology as Successful Nanotechnology 41 4.1 Molecular Motors in Large Animals: Linear Motors and Rotary Motors 41 4.2 Information Technology in Biology Based on DNA 46 4.3 Sensors, Rods, Cones, and Nanoscale Magnets 52 4.4 Ion Channels: Nanotransistors of Biology 53 References 53 5 The End of Scaling: The Lumpiness of All Matter in the Universe 55 5.1 Lumpiness of Macroscopic Matter below the 10- m Scale 55 5.2 Hydrogen Atom of Bohr: A New Size Scale, Planck s Constant 57 5.3 Waves of Water, Light, Electron, and Their Diffractions 60 5.4 DeBroglie Matter Wavelength 62 5.5 Schrodinger s Equation 63 5.6 The End of Scaling, the Substructure of the Universe 63 5.7 What Technologies Are Directly Based on These Fundamental Particles and Spin? 64 Reference 65 6 Quantum Consequences for the Macroworld 67 6.1 Quantum Wells and Standing Waves 67 6.2 Probability Distributions and Uncertainty Principle 69 6.3 Double Well as Precursor of Molecule 71 6.4 The Spherical Atom 73 6.5 Where Did the Nuclei Come From (Atoms Quickly Form around Them)? 75 6.6 The Strong Force Binds Nuclei 75 6.7 Chemical Elements: Based on Nuclear Stability 76 6.8 Molecules and Crystals: Metals as Boxes of Free Electrons 77 References 79 7 Some Natural and Industrial Self-Assembled Nanostructures 81 7.1 Periodic Structures: A Simple Model for Electron Bands and Gaps 81 7.2 Engineering Electrical Conduction in Tetrahedrally Bonded Semiconductors 83 7.3 Quantum Dots 85 7.4 Carbon Nanotubes 86 7.5 C60 Buckyball 91 References 92 8 Injection Lasers and Billion-Transistor Chips 93 8.1 Semiconductor P-N Junction Lasers in the Internet 93 8.2 P-N Junction and Emission of Light at 1.24 m 98 8.3 Field Effect Transistor 101 9 The Scanning Tunneling Microscope and Scanning Tunneling Microscope Revolution 105 9.1 Scanning Tunneling Microscope (STM) as Prototype 105 9.2 Atomic Force Microscope (AFM) and Magnetic Force Microscope (MFM) 110 9.3 SNOM: Scanning Near-Field Optical Microscope 115 10 Magnetic Resonance Imaging (MRI): Nanophysics of Spin 1/2 117 10.1 Imaging the Protons in Water: Proton Spin ., a Two-Level System 117 10.2 Magnetic Moments in a Milligram of Water: Polarization and Detection 118 10.3 Larmor Precession, Level Splitting at 1 T 119 10.4 Magnetic Resonance and Rabi Frequency 120 10.5 Schrodinger s Cat Realized in Proton Spins 121 10.6 Superconductivity as a Detection Scheme for Magnetic Resonance Imaging 122 10.7 Quantized Magnetic Flux in Closed Superconducting Loops 123 10.8 SQUID Detector of Magnetic Field Strength 124 A SQUID-Based MRI Has Been Demonstrated 125 11 Nanophysics and Nanotechnology of High-Density Data Storage 127 11.1 Approaches to Terabyte Memory: Mechanical and Magnetic 127 11.2 The Nanoelectromechanical Millipede Cantilever Array and Its Fabrication 127 11.3 The Magnetic Hard Disk 132 Reference 137 12 Single-Electron Transistors and Molecular Electronics 139 12.1 What Could Possibly Replace the FET at the End of Moore s Law ? 139 12.2 The Single-Electron Transistor (SET) 139 12.3 Single-Electron Transistor at Room Temperature Based on a Carbon Nanotube 142 12.4 Random Access Storage Based on Crossbar Arrays of Carbon Nanotubes 143 12.5 A Molecular Computer! 147 References 149 13 Quantum Computers and Superconducting Computers 151 13.1 The Increasing Energy Costs of Silicon Computing 152 13.2 Quantum Computing 152 13.3 Charge Qubit 154 13.4 Silicon-Based Quantum-Computer Qubits 155 13.5 Adiabatic Quantum Computation 157 Analog to Digital Conversion (ADC) Using RSFQ Logic 159 13.6 Opportunity for Innovation in Large-Scale Computation 160 References 161 14 Looking into the Future 163 14.1 Ideas, People, and Technologies 163 14.2 Why the Molecular Assembler of Drexler: One Atom at a Time, Will Not Work 166 14.3 Man-Made Life: The Bacterium Invented by Craig Venter and Hamilton Smith 169 14.4 Future Energy Sources 171 14.5 Exponential Growth in Human Communication 173 14.6 Role of Nanotechnology 175 References 175 Notes 177 Index 199