عنوان

Organometallic Compounds :

(Number (ISBN

9401168938

(Number (ISBN

9401168954

(Number (ISBN

9789401168939

(Number (ISBN

9789401168953

Number

b546262

Title Proper

Organometallic Compounds :

General Material Designation

[Book]

Other Title Information

Volume Two. The Transition Elements

First Statement of Responsibility

by G.E. Coates, M.L.H. Green, K. Wade.

Place of Publication, Distribution, etc.

Dordrecht

Name of Publisher, Distributor, etc.

Springer Netherlands

Date of Publication, Distribution, etc.

1968

Text of Note

To Volume Two --;Classification --;The 18-electron rule --;1. Two-Electron Ligands --;A. Classification --;B. The preparation of olefin-transition metal complexes --;C.A molecular orbital description of the bonding in organo-metallic complexes --;D.A description of the bonding of 2-electron ligands to transition metals --;E. General comments of 2-electron ligands --;F. Particular complexes of metals with 2-electron ligands --;2. Three-Electron Ligands --;A. Preparation of?-enyl complexes --;B. The structure of?-enyl complexes --;C. The?-allyl metal bond --;D. Dynamic equilibria in allyl complexes --;E. The chemistry of particular?-enyl complexes --;3. Four-Electron Ligands --;A. Some differences between unconjugated and conjugated olefin ligands --;B. The bonding of 4-electron ligands to transition metals --;C. Particular studies --;4. Five-Electron Ligands --;A. Cyclopentadienyl metal complexes --;B.?-Cyclopentadienyl transition metal complexes --;C. Cyclopentadienide transition metal complexes --;D. The bonding in mono-?-cyclopentadienyl transition metal complexes --;E.?-Cyclopentadienyl carbonyl complexes --;F.?-Cyclopentadienyl nitrosyl complexes --;G. Brief notes on binuclear?-cyclopentadienyl complexes containing bridging ligands --;H.?-Cyclopentadienyl hydride complexes --;I.?-Cyclopentadienyl halides and oxides --;J. Other 5-electron ligands --;K. The organic chemistry of?-cyclopentadienyl transition metal complexes --;L. Some particular reactions --;5. Six-Electron Ligands --;A. Arene transition metal complexes --;(a) Preparation --;B. Olefin 6-electron ligands --;C. Transition metal complexes containing?-bonded heterocyclic ligands --;6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes --;A. 7-Electron ligands --;B. Mixed sandwich complexes --;C. Metal complexes formed from azulenes --;D. Cyclo-octatetraene complexes --;7. One-Electron Ligands --;I.1. Hydrocarbon alkyl and aryl complexes --;I.2 Transition metal-acyl complexes --;I.3.?-Cyclopentadienyl complexes --;II. Transition metal fluorocarbon complexes --;III. Transition metal acetytides and alkynyls --;8. Organometallic Complexes Formed From Acetylenes --;A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands --;B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands --;C. Monoacetylene trinuclear complexes --;D. Monoacetylene tetranuclear complexes --;E. Bis-acetylene mononuclear complexes --;F. Bis-acetylene trinuclear complexes --;G. Tris-acetylene mononuclear complexes --;H. Tris-acetylene binuclear complexes --;I. Miscellaneous --;9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions --;A. Some chemistry of transition metal hydride complexes --;B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions --;C. Homogeneous hydrogenation of olefins and acetylenes --;D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes --;E. Hydroformylation and related carhonylation reactions --;F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts --;G. Miscellaneous --;Author --;Subject --;Crystal Structures>

Text of Note

Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p.

Physical Sciences & Mathematics.

Science (General)

Science.

Class number

Book number

by G.E. Coates, M.L.H. Green, K. Wade.

G E Coates

K Wade

M L H Green

Electronic name

[Book]

Y