عنوان

Organo main group chemistry /

(Number (ISBN

0470450339

(Number (ISBN

9780470450338

Number

dltt

Title Proper

Organo main group chemistry /

General Material Designation

[Book]

First Statement of Responsibility

Kin-ya Akiba

Specific Material Designation and Extent of Item

xi, 275 pages :

Other Physical Details

illustrations ;

Dimensions

24 cm

Text of Note

Includes bibliographical references and index

Text of Note

Main group elements and heteroatoms: scope and characteristics -- Notes 1: electronegativity -- Notes 2: importance of formal logic-I: oxidation number and formal charge -- Notes 3: importance of formal logic-II: octet rule, eighteen-electron rule, hypervalence -- Main group element effect -- Notes 4: ([lower case sigma, lower case sigma*) and (lower case pi, lower case pi*): HMO (Hueckel Molecular Orbital) and electrocyclic reaction -- Lithium, magnesium, and copper compounds -- Boron and aluminum compounds -- Silicon, tin, and lead compounds -- Notes 5: stable carbene and its complex -- Phosphorus,, antimony, and bismuth compounds -- Notes 6: dreams of Staudinger and Wittig -- Notes 7: stereochemistry in nucleophilic substitution of MX₄-type compounds: inversion or retention -- Sulfur, selenium, and tellurium compounds -- Notes 8: inversion mechanism of NH₃ and NF₃: vertex inversion or edge inversion -- Organohalogen compounds: fluorine and iodine compounds -- Atrane and transannular interaction: formation of hypervalent bond -- Unsaturated compounds of main group elements of third period and heavier -- Ligand coupling reaction -- Notes 9: hexavalent organotellurium compounds -- Hypervalent carbon compounds: can hexavalent carbon exist? -- Notes 10: main group element porphyrins

0

Text of Note

"This book will capture the essential scope of organic chemistry of all main group elements and covers all main group elements dealing with syntheses and reactions of their organic compounds. While organic compounds of second row elements centered at carbon are the major components of animals and plants, those of the third row and below are also important and have unique roles which this book discusses. The first eight chapters are arranged according to the periodic table, starting with the role of lithium and magnesium cations (positively charged ions) in synthesis to fluorine and iodine compounds. The last four chapters deal with modern topics that were selected on the basis of unique characteristics of main group elements compared to the carbon (i.e. main group element effect is placed as the central idea to arrange and unify.)"--

Carbon compounds

Chemistry, Organic

Organic compounds

Organic compounds-- Synthesis

Class number

Book number

Akiba, Kinʼya,1936-

Date of Transaction

20120428035303.0

Cataloguing Rules (Descriptive Conventions))

rda

Electronic name

[Book]

Y