عنوان

Matrix Isolation Spectroscopy

(Number (ISBN

9789400985407

(Number (ISBN

9789400985421

Number

b408618

Title Proper

Matrix Isolation Spectroscopy

General Material Designation

[Book]

Other Title Information

A book based on the lectures given and the discussions that took place at the NATO Advanced Study Institute held at the Université des Sciences et Techniques du Languedoc,Montpellier, France, July 17-31,1980 /

First Statement of Responsibility

edited by A. J. Barnes, W. J. Orville-Thomas, A. Müller, R. Gaufrès.

Place of Publication, Distribution, etc.

Dordrecht :

Name of Publisher, Distributor, etc.

Springer Netherlands,

Date of Publication, Distribution, etc.

1981.

Series Title

NATO Advanced Study Institutes Series, Series C - Mathematical and Physical Sciences,

Volume Designation

76

ISSN of Series

1389-2185 ;

Text of Note

1. The history of matrix isolation spectroscopy. -- Section A - Techniques -- 2. Infrared and Raman matrix isolation spectroscopy. -- 3. Electronic spectroscopy of matrix isolated solutes. -- 4. Magnetic circular dichroism - matrix isolation spectroscopy. -- 5. Electron spin resonance studies of radicals trapped in rare-gas matrices. -- 6. Mössbauer spectroscopy on matrix-isolated species -- 7. Time and frequency resolved vibrational spectroscopy of matrix isolated molecules: Population and phase relaxation processes. -- 8. Stable molecules. -- 9. Generation and trapping of unstable solutes in low temperature matrices. -- 10. The characterisation of high temperature molecules using matrix isolation and vibrational spectroscopy. -- 11. High pressure studies. -- 12. Non-traditional matrix isolation: adducts. -- Section B - Matrix Effects -- 13. Interpretation of infrared and Raman spectra of trapped molecular impurities from interaction potential calculations. -- 14. Matrix induced changes in the electronic spectra of isolated atoms and molecules. -- 15. Matrix effects studied by electron spin resonance spectroscopy. -- 16. Molecular motion in matrices. -- 17. Vibrational band intensities in matrices. -- Section C - Applications -- 18. Matrix isolation spectroscopy of metal atoms and small clusters. -- 19. Vibrational spectra of matrix isolated gaseous ternary oxides. -- 20. Matrix isolation spectra (IR, Raman) of transition metal compounds. -- 21. Metal carbonyls - structure, photochemistry, and IR lasers. -- 22. Matrix isolation vibrational spectroscopy on organic molecules. -- 23. Conformational isomerism studied by matrix isolation vibrational spectroscopy. -- 24. Hydrogen bonding in matrices. -- Author Index.

0

Text of Note

The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.

International Standard Book Number

9789400985421

Title

Springer eBooks

Parallel Title

A book based on the lectures given and the discussions that took place at the NATO Advanced Study Institute, Université des Sciences et Techniques du Languedoc, Montpellier, France, July 17-31, 1980

Chemistry.

Barnes, A. J.

Gaufrès, R.

Müller, A.

Orville-Thomas, W. J.

SpringerLink (Online service)

Date of Transaction

20190307155400.0

Electronic name

[Book]

Y