عنوان

Emulsification and polymerization of alkyd resins

Standard Number

electronic

First Statement of Responsibility

Gooch, Jan W. )Jan Woodall(

Title Proper by Another Author

6491-

Title Proper

Emulsification and polymerization of alkyd resins

Place of Publication, Distribution, etc.

New York

Name of Publisher, Distributor, etc.

Kluwer Academic/Plenum Publishers

Date of Publication, Distribution, etc.

2002

Specific Material Designation and Extent of Item

xxii, 223 p. : ill. ; 24 cm

Series Title

Topics in applied chemistry

Text of Note

Includes bibliographical references )p. 215-218( and index

Text of Note

Jan W. Gooch

Text of Note

Machine generated contents note: I -- I -- 1. ALKYD RESINS, VEGETABLE OILS AND AUTOXIDATIVE -- POLYMERIZATION -- 1.1. Goals of Research and Development in Alkyd Emulsions -- 1.2. Historical Background of Alkyds, Oils and Emulsions -- 1.2.1. Vegetable Oils and Resins -- 1.2.2. Autoxidative Polymerization of Vegetable Oils and -- Resins -- 1.2.3. Emulsified Oils and Resins -- 1.3. Theoretical Considerations -- 1.3.1. Intrinsic Viscosity -- 1.3.2. Hydrophile-Lipophile Balance )HLB( -- 1.3.3. Diffusion of Oxygen in an Emulsion -- 1.3.4. Solubility of Air and Oxygen in Aqueous Phase -- 1.3.5. Swelling Ratio -- 1.4. Justification for Research and Development -- 2. SYNTHESIS AND POLYMERIZATION OF ALKYDS -- 2.1. Alkyd Synthesis Procedure -- 2.2. Emulsification Procedure -- 2.3. Autoxidation Procedure -- 2.4. Materials -- 2.5. Characterization -- 2.5.1. Emulsion Particle Size -- 2.5.2. Emulsion Characterization -- 2.5.3. Film Characterization -- 2.5.4. Intrinsic Viscosity Measurement -- 2.5.5. Swell Ratio -- 2.5.6. Turbidimetric Measurement of Swelling Ratio -- 2.5.7. Dissolved Oxygen in Aqueous Phase -- 3. EMULSION AND KINETIC STUDIES OF AUTOXIDATIVE -- POLYMERIZATION -- 3.1. Emulsifier Studies -- 3.1.1. Emulsifier Sources and Chemical Structures -- 3.1.2. Emulsifiers and Emulsion Stability -- 3.1.3. Emulsifiers and Freeze-Thaw Stability -- 3.1.4. Emulsifiers and Film Characterization -- xiii -- 3.2. Phase Ratio and Co-Solvent Study -- 3.2.1. Solvent Alkyd Emulsions -- 3.2.2. Co-Solvent Containing Emulsions -- 3.3. Studies on the Autoxidative Crosslinking of Emulsified -- Soya Oil -- 3.3.1. Autoxidation Reaction of Emulsified Soya Oil -- 3.3.2. Catalysis of Autoxidation Reaction of Soya Oil -- 3.4. Studies of the Autoxidative Crosslinking of Emulsified -- Alkyd Particles -- 3.4.1. Autoxidation Reaction of Emulsified Alkyd Resins -- 3.4.2. Non-catalyzed Autoxidation Reaction -- 3.4.3. Benzoyl Peroxide Catalysis in the Alkyd Phase -- 3.4.4. Cobalt Naphthenate Catalysis in Aqueous Phase -- 3.4.5. Autoxidized Emulsion Characterization -- 3.4.6. Post pH-Adjustment of Autoxidized Emulsion -- 3.4.7. pH Adjustment Prior to the Autoxidation -- 3.4.8. Cobalt Naphthenate Catalysis in Alkyd Phase -- 3.4.9. Post-Addition of Emulsifier -- 3.4.01. pH Effect on Reaction Rate -- 3.4.11. Increased Oxygen Concentration and Catalysis -- 3.4.21. Scanning Electron Microscopy -- 3.4.31. Water Clean-Up of Emulsion -- 3.4.41. Comparison to Alkyd-Solvent System -- 3.4.51. Effect of Emulsifier Structure on Reaction Rate -- 3.5. Kinetic Study -- 3.5.1. Oxygen Concentration Relationship -- 3.5.2. Correlation of Swell Ratio and Percent Transmittance -- 3.5.3. Catalysis Effect -- 3.5.4. Temperature Effect -- 3.5.5. Agitation Rate Effect -- 3.5.6. Molecular Weight Effect -- 3.6. Studies on Emulsion Particle Size -- 3.6.1. Particle Size with Reaction Time -- 3.6.2. Average Particle Size with Homogenization -- 3.6.3. Particle Size after One Year of Shelf Life -- 3.7. Alkyd Oil Length and Conjugation Study -- 3.7.1. Alkyd Oil Length Study -- 3.7.2. Alkyd Conjugation Study -- 4. EXPERIMENTAL RESULTS, RESEARCH -- AND COMMERCIALIZATION OF TECHNOLOGY -- 4.1. Autoxidative Crosslinking of Vegetable Oil -- 4.2. Autoxidative Crosslinking of Vegetable Oil Alkyds -- 4.3. Emulsification -- 4.4. Continuing Research and Developments -- 4.5. Commercialization of Alkyd Emulsions -- APPENDIX - FIGURES -- APPENDIX - TABLES -- REFERENCES -- INDEX

Entry Element

، Alkyd resins

Entry Element

، Emulsification

Class number

Relator Code

AU

TI

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