عنوان
پدید آورنده
موضوع
رده
کتابخانه
محل استقرار
شماره کتابشناسی ملی
شماره
TL51187
زبان اثر
زبان متن نوشتاري يا گفتاري و مانند آن
انگلیسی
عنوان و نام پديدآور
عنوان اصلي
Structural Characterization and Manipulation of Chiral Nanosamples Using Structured Light and Optical Force
نام عام مواد
[Thesis]
نام نخستين پديدآور
Kamandi, Mohammad
نام ساير پديدآوران
Capolino, Filippo
وضعیت نشر و پخش و غیره
نام ناشر، پخش کننده و غيره
University of California, Irvine
تاریخ نشرو بخش و غیره
2019
يادداشت کلی
متن يادداشت
133 p.
یادداشتهای مربوط به پایان نامه ها
جزئيات پايان نامه و نوع درجه آن
Ph.D.
کسي که مدرک را اعطا کرده
University of California, Irvine
امتياز متن
2019
یادداشتهای مربوط به خلاصه یا چکیده
متن يادداشت
Detection, characterization and separation of chiral structures as one of the fundamental constituents of biomolecules are crucial in chemical and biological applications. Conventionally, chiroptical techniques such as circular dichroism (CD) are exploited to identify the material chirality. These methods require substantial amount of sample material with a high concentration. since chirality effect (as an indirect electric to magnetic coupling between incident light and sample material) is typically very weak. Therefore, the observation of chirality might be masked under the electric properties in chiroptical techniques if a substantial amount of material is not provided. Consequently, these techniques are not suitable for detection of chirality for nanoscale samples and can't provide information about their primary or secondary structure. On the other hand, separation of enantiomers is of great interest in pharmaceutical applications. Classical separation techniques which are used to separate molecular compounds and complexes in achiral environment, such as liquid-liquid extraction, chromatography and distillation are not universal for separation of all types of chiral molecules/compounds since not all compounds and host media are chemically compatible. This dissertation focuses on introducing new techniques for detection, characterization and manipulation of chiral nanoparticles and nanostructures using structured light. Specifically, a new technique involving the measurement of photo-induced optical force (near-field characteristics) rather than the measurement of conventional scattered power (far-field characteristics) is introduced which substantially enhances the resolution in the detection of enantiomer type of chiral samples down to sub-100 nm. Furthermore, by utilizing structured illumination (circularly polarized wave for detection of transverse chirality and combination of azimuthally and radially polarized waves in the so-called azimuthally-radially polarized beam for detection of longitudinal chirality) the prediction of spatial features of the structure of a chiral sample is facilitated. It's been demonstrated that circularly polarized illumination can't differentiate between chirality and anisotropy. To overcome this deficiency and differentiate between anisotropy and chirality, an engineered combination of vortex beams (ARPB) is utilized. Lastly, a novel scheme to manipulate and control chiral nanoparticles and to sort enantiomers is proposed.
اصطلاحهای موضوعی کنترل نشده
اصطلاح موضوعی
Applied physics
اصطلاح موضوعی
Electrical engineering
اصطلاح موضوعی
Nanoscience
اصطلاح موضوعی
Nanotechnology
اصطلاح موضوعی
Optics
اصطلاح موضوعی
Organic chemistry
اصطلاح موضوعی
Physical chemistry
نام شخص به منزله سر شناسه - (مسئولیت معنوی درجه اول )
مستند نام اشخاص تاييد نشده
Kamandi, Mohammad
نام شخص - ( مسئولیت معنوی درجه دوم )
مستند نام اشخاص تاييد نشده
Capolino, Filippo
شناسه افزوده (تنالگان)
مستند نام تنالگان تاييد نشده
University of California, Irvine
دسترسی و محل الکترونیکی
نام الکترونيکي
مطالعه متن کتاب وضعیت انتشار
فرمت انتشار
p
اطلاعات رکورد کتابشناسی
نوع ماده
[Thesis]
کد کاربرگه
276903
اطلاعات دسترسی رکورد
سطح دسترسي
a
تكميل شده
Y
