عنوان

Solid-State NMR in zeolite catalysis /

9789811369650

9789811369667

9789811369674

9811369658

9811369666

9811369674

9789811369650

Solid-State NMR in zeolite catalysis /

[Book]

Jun Xu, Qiang Wang, Shenhui Li and Feng Deng.

Singapore :

Springer,

[2019]

©2019

1 online resource

Lecture notes in chemistry ;

Volume 103

Includes bibliographical references and index.

Intro; Preface; Contents; 1 Solid-State NMR Principles and Techniques; 1.1 Introduction; 1.2 Nuclear Spin Interactions in Solids; 1.2.1 Chemical Shift Interaction; 1.2.2 Dipole-Dipole Interaction; 1.2.3 Quadrupolar Interaction; 1.2.4 Spin-Spin Interaction; 1.3 Manipulations of Spin Interactions in Solids; 1.3.1 Magic-Angle Spinning (MAS); 1.3.2 Cross-Polarization; 1.3.3 Dipolar Decoupling Methods in Rotating Solid; 1.3.4 Dipolar Recoupling Methods in Rotating Solid; 1.3.5 High-Resolution Techniques for Half-Integer-Spin Quadrupolar Nuclei; 1.3.6 Summary; References

2 Solid-State NMR Studies of Zeolites and Zeotype Materials Synthesis2.1 Introduction; 2.2 Zeolite Synthesis Route and Procedures; 2.3 Zeolite Synthesis Process and Crystallization Mechanism; 2.4 NMR Strategy in Characterization of Zeolite Synthesis; 2.4.1 Microporous Aluminosilicates; 2.4.2 Microporous Aluminophosphates; 2.5 Summary; References; 3 Solid-State NMR Characterization of Framework Structure of Zeolites and Zeotype Materials; 3.1 Introduction; 3.2 Solid-State NMR Characterization of Zeolite Framework Structure; 3.2.1 27Al MAS NMR; 3.2.2 29Si MAS NMR; 3.2.3 31P MAS NMR

3.2.4 17O MAS NMR3.2.5 129Xe NMR; 3.2.6 Other Framework Elements; 3.3 Summary; References; 4 Solid-State NMR Characterization of Host-Guest Interactions; 4.1 Introduction; 4.2 Solid-State NMR Characterization of Host-Guest Interactions; 4.2.1 Host-Guest Interaction Between Adsorbed Molecule and Zeolite Framework; 4.2.2 Host-Guest Interaction in Molecular Sieve Synthesis; 4.2.3 Host-Guest Interaction in Zeolite Catalysis; 4.3 Summary; References; 5 Solid-State NMR Characterization of Acid Properties of Zeolites and Solid Acid Catalysts; 5.1 Introduction

5.2 Solid-State NMR Characterization of Acidic Property5.2.1 Acid Sites Containing Hydroxyl Groups; 5.2.2 Acidic Nature and Strength; 5.2.3 Location and Distribution of Acid Sites; 5.2.4 Spatial Proximities and Synergy Effects of Different Acid Sites; 5.3 Summary; References; 6 In Situ Solid-State NMR Investigation of Catalytic Reactions on Zeolites; 6.1 Introduction; 6.2 In Situ Solid-State NMR Approaches; 6.2.1 Batch Reaction; 6.2.2 Flow Reaction; 6.3 Mechanistic Study of the Catalytic Reactions by In Situ NMR; 6.3.1 Activation and Conversion of Light Alkanes

6.3.2 Methanol-to-Olefins (MTO) Conversion6.4 Summary; References; Index

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Solid-State NMR Characterization of Heterogeneous Catalysts and Catalytic Reactions provides a comprehensive account of state-of-the-art solid-state NMR techniques and the application of these techniques in heterogeneous catalysts and related catalytic reactions. It includes an introduction to the basic theory of solid-state NMR and various frequently used techniques. Special emphasis is placed on characterizing the framework and pore structure, active site, guest-host interaction, and synthesis mechanisms of heterogeneous catalysts using multinuclear one- and two-dimensional solid-sate NMR spectroscopy. Additionally, various in-situ solid-state NMR techniques and their applications in investigation of the mechanism of industrially important catalytic reactions are also discussed. Both the fundamentals and the latest research results are covered, making the book suitable as a reference guide for both experienced researchers in and newcomers to this field. Feng Deng is a Professor at Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences.

Springer Nature

com.springer.onix.9789811369674

9789811369650

9789811369667

Nuclear magnetic resonance spectroscopy.

Zeolite catalysts.

BUSINESS & ECONOMICS-- Industries-- General.

Nuclear magnetic resonance spectroscopy.

Zeolite catalysts.

BUS-- 070000

PNRD

PNRD

Xu, Jun

Deng, Feng

Li, Shenhui

Wang, Qiang

20200823232946.0

pn

[Book]

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