Advances in Hydrogen Production and Storage (AHPS) Ser.
3.6 Novel Mg-TM (TM=V, Zn, Al) Nanocomposites.
Cover; Title Page; Copyright Page; Contents; Preface; Part I: Chemical and Electrochemical Hydrogen Storage; 1 Metal Hydride Hydrogen Compression Systems -- Materials, Applications and Numerical Analysis; 1.1 Introduction; 1.2 Adoption of a Hydrogen-Based Economy; 1.2.1 Climate Change and Pollution; 1.2.2 Toward a Hydrogen-Based Future; 1.2.3 Hydrogen Storage; 1.2.3.1 Compressed Hydrogen Storage; 1.2.3.2 Hydrogen Storage in Liquid Form; 1.2.3.3 Solid-State Hydrogen Storage; 1.3 Hydrogen Compression Technologies; 1.3.1 Reciprocating Piston Compressor; 1.3.2 Ionic Liquid Piston Compressor.
1.3.3 Piston-Metal Diaphragm Compressor1.3.4 Electrochemical Hydrogen Compressor; 1.4 Metal Hydride Hydrogen Compressors (MHHC); 1.4.1 Operation of a Two-Stage MHHC; 1.4.2 Metal Hydrides; 1.4.3 Thermodynamic Analysis of the Metal Hydride Formation; 1.4.3.1 Pressure-Composition-Temperature (P-c-T) Properties; 1.4.3.2 Slope and Hysteresis; 1.4.4 Material Challenges for MHHCs; 1.4.4.1 AB5 Intermetallics; 1.4.4.2 AB2 Intermetallics; 1.4.4.3 TiFe-Based AB-Type Intermetallics; 1.4.4.4 Vanadium-Based BCC Solid Solution Alloys; 1.5 Numerical Analysis of a Multistage MHHC System; 1.5.1 Assumptions.
1.5.2 Physical Model and Geometries1.5.3 Heat Equation; 1.5.4 Hydrogen Mass Balance; 1.5.5 Momentum Equation; 1.5.6 Kinetic Expressions for the Hydrogenation and Dehydrogenation; 1.5.7 Equilibrium Pressure; 1.5.8 Coupled Mass and Energy Balance; 1.5.9 Validation of the Numerical Model; 1.5.10 Material Selection for a Three-Stage MHHC; 1.5.11 Temperature Evolution of the Complete Three-Stage Compression Cycle; 1.5.12 Pressure and Storage Capacity Evolution During the Complete Three-Stage Compression Cycle; 1.5.13 Importance of the Number of Stages and Proper Selection; 1.6 Conclusions.
2.3.2 NH3 Solid-State Storage2.3.2.1 Metal Ammine Salts; 2.3.2.2 Ammine Metal Borohydride; 2.3.3 NH3 Decomposition; 2.3.4 Application of NH3 to Fuel Cell; 2.4 Future Prospects; References; 3 Nanostructured Mg-Based Hydrogen Storage Materials: Synthesis and Properties; 3.1 Introduction; 3.2 Experimental Details; 3.2.1 Synthesis of Metal Nanoparticles; 3.2.2 Formation of the Nanostructured Hydrides and Alloys; 3.2.3 Characterization and Measurements; 3.3 Synthesis Results of the Nanostructured Samples; 3.4 Hydrogen Absorption Kinetics; 3.5 Hydrogen Storage Thermodynamics.