edited by Pascal Van Der Voort (Ghent University, Ghent, Belgium), Karen Leus (Ghent University, Ghent, Belgium), Els De Canck (Recticel NV Insulation, Belgium).
1 Nature's Porous Materials: From Beautiful to Practical; 1.1 Living Porosity; 1.2 Clay Minerals; References; 2 Theory of Adsorption and Catalysis: Surface Area and Porosity; 2.1 Determination of Surface Area and Porosity by Gas Sorption; 2.2 The BET (Brunauer, Emmet, Teller) Model; 2.3 Capillary Condensation and Pore Size, the Type IV Isotherm; 2.4 Liquid Phase Adsorption -- Langmuir and Freundlich Isotherms; 2.5 Heterogeneous Catalysis; Appendix; Exercises; Answers to the Problems; References; 3 Zeolites and Zeotypes
3.1 Crystallographic Directions and Planes3.2 X-Ray Diffraction; 3.3 Zeolite Structures; 3.4 Applications of Zeolites; 3.5 Solid-State NMR; References; 4 Silica, A Simple Oxide -- A Case Study for FT-IR Spectroscopy; 4.1 Different Methods to Synthesize Silica; 4.2 The Surface of Silica; 4.3 Fourier Transform Infrared Spectroscopy; References; 5 Ordered Mesoporous Silica; 5.1 MCM-41 and MCM-48 -- Revolution by the Mobil Oil Company; 5.2 Applications of Mesoporous Silica; References; 6 Carbons; 6.1 Activated Carbon; 6.2 General Introduction to Mesoporous Carbons
6.3 Surface Modification of Mesoporous Polymers and Carbons6.4 Nanocarbons; 6.5 Application of Porous Carbon-Based Materials; References; 7 The Era of the Hybrids -- Part 1: Periodic Mesoporous Organosilicas or PMOS; 7.1 Introduction; 7.2 Synthesis of PMOs; 7.3 General Properties of PMOs; 7.4 Post-Modification of PMOs; 7.5 Applications of PMOs; References; 8 Era of the Hybrids -- Part 2: Metal-Organic Frameworks; 8.1 Introduction; 8.2 Isoreticular Synthesis; 8.3 Well-Known MOFs; 8.4 Stability of MOFs; 8.5 Preparation of MOFs; 8.6 Functionalities in MOFs; 8.7 Applications of MOFs
8.8 Industrial Applications of MOFs8.9 Transmission Electron Microscopy; Exercises; Answers to the Problems; References; 9 Beyond the Hybrids -- Covalent Organic Frameworks; 9.1 Classification and Nature of COFs; 9.2 Design of COFs; 9.3 Boron-Based COFs; 9.4 Covalent Triazine Frameworks; 9.5 Imine COFs; References; Index; End User License Agreement
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The first comprehensive textbook on the timely and rapidly developing topic of inorganic porous materials This is the first textbook to completely cover a broad range of inorganic porous materials. It introduces the reader to the development of functional porous inorganic materials, from the synthetic zeolites in the 50's, to today's hybrid materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and related networks. It also provides the necessary background to understand how porous materials are organized, characterized, and applied in adsorption, catalysis, and many other domains. Additionally, the book explains characterization and application from the materials scientist viewpoint, giving the reader a practical approach on the characterization and application of the respective materials. Introduction to Inorganic Porous Materials begins by describing the basic concepts of porosity and the different types of pores, surfaces, and amorphous versus crystalline materials, before introducing readers to nature's porous materials. It then goes on to cover everything from adsorption and catalysis to amorphous materials such as silica to inorganic carbons and Periodic Mesoporous Organosilicas (PMOs). It discusses the synthesis and applications of MOFs and the broad family of COFs. It concludes with a look at future prospects and emerging trends in the field. -The only complete book of its kind to cover the wide variety of inorganic and hybrid porous materials -A comprehensive reference and outstanding tool for any course on inorganic porous materials, heterogeneous catalysis, and adsorption -Gives students and investigators the opportunity to learn about porous materials, how to characterize them, and understand how they can be applied in different fields Introduction to Inorganic Porous Materials is an excellent book for students and professionals of inorganic chemistry and materials science with an interest in porous materials, functional inorganic materials, heterogeneous catalysis and adsorption, and solid state characterization techniques.