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کتابخانه
محل استقرار
TLets461578
The alkaline hydrolysis of esters in aqueous-organic solvent mixtures :
[Thesis]
Kazempour, Abdol Rassoul
the effects of solvents and of the activity coefficients of reactants on the kinetics of the alkaline hydrolysis of methyl acetate in aqueous dioxan, aqueous dimethyl sulphoxide and aqueous diglyme (bis (2-methoxyethyl ) ether) mixtures as solvents
Diaper, John
University of Bradford
1978
Thesis (Ph.D.)
1978
Values of the rate constant for the alkaline hydrolysis of methyl acetate in various aqueous-organic solvent mixtures (dimethyl sulfoxide 0 aH 20> YOH_/YM+ -> (dielectric constant), and that the nonelectrostatic effects -- thermodynamic effects - are more important in these studies than the electrostatic effects. From a preliminary investigation of the data in the literature the thermodynamic approach also yields a valid interpretation of the effect of solvent composition on the rates of the acid hydrolysis of esters.
Methyl acetate ; Alkaline hydrolysis ; Aqueous-organic solvent mixtures ; Activity coefficients ; Bronsted-Bjerrum equation ; Residual activity coefficient ratio
Kazempour, Abdol Rassoul
Diaper, John
University of Bradford
مطالعه متن کتاب p
[Thesis]
276903
a
Y
