Preparation and Properties of Stereoregular Polymers Based upon the Proceedings of the NATO Advanced Study Institute Held at Tirrennia, Pisa, Italy, October 3-14, 1978.
[Book]
Lenz, R.W.
Springer Verlag
2013
I. Stereoregular Polymers Synthesis and Polymerization Mechanism.- l. Stereoregular Polymers:Stereochemical Aspects and Synthetic Approaches.- 2.Recent Developments in Stereoregulation by Ziegler-Natta Polymerization of ?-Olefins.- 3.Kinetic Considerations and Active Centre Determinations in Ziegler-Natta Polymerization.- 4. New Supported Catalysts for Stereoregular Polymerization of ?-Olefins.- 5. The Control of Diolefins Selective Polymerization.- 6. Stereochemistry of the Metathesis Reaction of Olefins.- 7. Stereoregulation of Homogeneous Free Radical, Cationic and Anionic Polymerization Reactions.- 8. Coexistence of Active Species in Anionic Polymerization of Ethyl Methacrylate.- 9. Ion Pair Effects on the Anionic Oligomerization. Stereochemistry of Vinyl Pyridines and Related Monomers.- 10. Auto- and Induced Stereoregulation of Polyisocyanides.- 11. Present Understanding of the Stereospecific Polymerization of Cyclic Monomers: Three-Member Rings.- 12. Present Understanding of the Stereospecific Polymerization of Cyclic Monomers:Large Rings.- 13. Stereoregular Polymers from Substituted ?-Lactones and ?-Lactams.- II.Characterization and Properties of Stereoregular Polymers.- 14.Physical and Mechanical Properties of Optically Active and Racemic Poly( ?-Methyl- ?-n-Propyl- ?- Propiolactone).- 15.NMR Analysis of Stereoregular Homopolymers.- l6.NMR Analysis of Stereoregular Copolymers.- 17.Present Status of the Configurational and Conformational Analysis of Stereoregular Polymers.- 18. Application of Chiroptical Properties to Conformational Analysis of Stereoregular Polymers..- 19.Recent Developments of Vibrational Spectroscopy of Polymers.-Dynamics and Spectra of Disordered Polymers..- 20.The Crystalline Structure of Addition Polymers. Recent Research Results.- 21.New Insights and Unsolved Problems in the Crystalline Structure of Polyesters.- 22.Present Understanding of the Viscoelastic and Mechanical Properties of Stereoregular Polymers..- 23.Effect of Stereoregularity on Bulk Properties of Polymers.- Index of Subjects.