عنوان

Molecular Design of Tautomeric Compounds

9400914296

9789400914292

b595523

Molecular Design of Tautomeric Compounds

[Book]

edited by V.I. Minkin, L.P. Olekhnovich, Yu. A. Zhdanov.

Dordrecht

Springer Netherlands

1988

(312 pages)

Understanding chemical reactivity, 3.

1. The Problem of Tautomerism --; 1. Tautomerism as Dynamic Isomerism --; 2. Degenerate Tautomerism --; 3. Methods for Investigating Tautomeric Systems --; 4. Butlerov's and Laar's Tautomeric Systems --; 5. Tautomerism and the Mechanisms of Organic Reactions --; 6. Classification of Tautomeric Reactions --; 7. Conclusion --; References --; 2. Carbonotropy --; 1. The Problem of Carbonotropy --; 2. Sigmatropic Acyl and Aryl Rearrangements --; 3. Acylotropic Tautomerism --; 4. Tautomeric Rearrangements of Aryl Groups --; 5. Carbonotropic Tautomerism in Ions, Radicals and Cyclopolyenes --; References --; 3. General Principles of the Design of Tautomeric Systems --; 1. Possibilities of Quantum Mechanical Prediction of Tautomeric Reactions --; 2. Stereochemical Approach to the Design of Tautomeric Compounds --; References --; 4. The Mechanisms of Nucleophilic Substitution at the Main Group Element and Design of Intramolecular Tautomeric Systems --; 1. Tautomeric Rearrangements of Carbon-containing Groups --; 2. Silylotropic Tautomerism --; 3. Tautomeric Migrations of Phosphorus-containing Groups --; 4. Tautomeric Rearrangements of As-containing Groups --; 5. Tautomeric Rearrangements of Sulfur-containing Groups --; References --; 5. Dyotropic and Polytropic Tautomeric Systems --; 1. Scope and Definition --; 2. The Mechanism and Energetics of the Dyotropic Reactions --; References --; 6. Dissociative and Photochemical Mechanisms of Intramolecular Tautomerism --; 1. Heterolytic Dissociative Mechanism --; 2. Homolytic Dissociative Mechanism --; 3. Ion-Radical Mechanism --; 4. Photo-Initiated Carbonotropic Rearrangements --; References.

Chemistry.

Physical organic chemistry.

edited by V.I. Minkin, L.P. Olekhnovich, Yu. A. Zhdanov.

I︠U︡ A Zhdanov

L P Olekhnovich

V I Minkin

[Book]

Y