عنوان

Vibronic Interactions in Molecules and Crystals

354019259X

3642834795

9783540192596

9783642834790

b574426

Vibronic Interactions in Molecules and Crystals

[Book]

edited by Isaac B. Bersuker, Victor Z. Polinger.

Berlin, Heidelberg

Springer Berlin Heidelberg

1989

(xii, 422 pages 86 illustrations)

Springer series in chemical physics, 49.

Introduction --; Vibronic Interactions and the Jahn-Teller Theorem --; Adiabatic Potentials --; Solution of Vibronic Equations. Tunneling Splitting --; Spectroscopic Manifestations of Vibronic Effects --; Cooperative Phenomena. Structural Phase Transitions --; Appendices --; References --; Subject Index.

The theory of vibronic interactions is a new field of investigation in the physics and chemistry of molecules and crystals that goes beyond the separate descriptions of the motion of electrons and nuclei in the adiabatic approximation. A systematic treatment of the most important manifestations of nonadiabaticity (the Jahn-Teller, pseudo-Jahn-Teller and Renner effects) is given, including derivation of the vibronic Hamiltonian, proof of the Jahn-Teller theorem, determination of the adiabatic potentials of electronically degenerate and pseudodegenerate polyatomic systems, calculations of vibronic energy spectra and solutions of the multimode and multicenter problems. The second part of the book contains applications of the theory to optical and infrared spectroscopy, EPR and cooperative phenomena in crystals.

Crystallography.

Physics.

edited by Isaac B. Bersuker, Victor Z. Polinger.

I B Bersuker

Victor Z Polinger

[Book]

Y