عنوان

Fluxional organometallic and coordination compounds /

0470858397

9780470858394

dltt

Fluxional organometallic and coordination compounds /

[Book]

edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer

xvi, 323 pages :

illustrations ;

24 cm

Physical organometallic chemistry ;

v. 4

Includes bibliographical references and index

Polyhedral dynamics and the Jahn-Teller effect / R. Bruce King -- NMR studies of intramolecular dynamics in allylic type triorganoboranes / Ilya D. Gridnev -- Dynamic behavior of group 5 and 6 transition metal complexes by NMR / Sergei Sakarov -- Conformational mobility in chelated square-planar Rh, Ir, Pd, and Pt complexes / Pablo Espinet and Juan A. Casares -- Dynamic and kinetic aspects of metallodrugs by NMR / Fei Li and Hongzhe Sun -- Dynamics by EPR : picosecond to microsecond time scales / Sabine Vandoorslaer and Gunnar Jeschke -- USR studies of molecular dynamics in organometallics / Upali A. Jayasooriya -- Proton dynamics in solids : vibrational spectroscopy with neutrons / François Fillaux

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This series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry._ This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach._The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences.

Provides information on some of the most relevant physical methods for studying dynamic processes Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications Connects main group, transition metal and solid state chemistry in the question for dynamics

Coordination compounds

Molecular dynamics

Nuclear magnetic resonance spectroscopy

Organometallic chemistry

Gielen, M., (Marcel),1938-

Willem, R., (Rudolf)

Wrackmeyer, Bernd,1947-

20160712073249.0

[Book]

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