عنوان
پدید آورنده
موضوع
رده
TP1180.P68 M36 2012
TP1180
.
P68
M36
2012
کتابخانه
محل استقرار
1118062760
1118463188 (electronic bk.)
1118463218 (electronic bk.)
9781118062760
9781118463185 (electronic bk.)
9781118463215 (electronic bk.)
b429266
Introduction to industrial polypropylene :
[Book]
properties, catalysts, processes /
Dennis B. Malpass and Elliot I. Band.
1 online resource (356 pages)
Includes bibliographical references and index
Introduction to Industrial Polypropylene: Properties, Catalysts, Processes; Contents; List of Tables; List of Figures; Preface; 1 Introduction to Polymers of Propylene; 1.1 Origins of Crystalline Polypropylene; 1.2 Basic Description of Polypropylene; 1.3 Types and Nomenclature of Polypropylene; 1.4 Molecular Weight of Polypropylene; 1.5 Transition Metal Catalysts for Propylene Polymerization; 1.6 Questions; References; 2 Polymer Characterization; 2.1 Introduction; 2.2 Polymer Tacticity; 2.2.1 Introduction; 2.2.2 Measurement of Polymer Microtacticity by 13C NMR; 2.2.3 Total Isotactic Index
2.2.4 Total Xylene Insolubles; 2.3 Molecular Weight and Molecular Weight Distribution; 2.3.1 Introduction; 2.3.2 Gel Permeation Chromatography; 2.3.3 Intrinsic Viscosity; 2.3.4 Melt Flow Rate; 2.4 Polymer Bulk Density; 2.4.1 Introduction; 2.4.2 Measurement Method; 2.5 Particle Size Distribution and Morphology; 2.5.1 Introduction; 2.5.2 Measurement Method; 2.6 Questions; References; 3 Ziegler-Natta Catalysts; 3.1 A Brief History of Ziegler-Natta Catalysts; 3.2 Definitions and Nomenclature; 3.3 Characteristics of Ziegler-Natta Catalysts; 3.4 Early Commercial Ziegler-Natta Catalysts
3.5 Supported Ziegler-Natta Catalysts; 3.6 Prepolymerized Ziegler-Natta Catalysts; 3.7 Mechanism of Ziegler-Natta Polymerization; 3.8 Questions and Exercises; References; 4 Propylene Polymerization Catalysts; 4.1 Introduction; 4.2 Zero Generation Ziegler-Natta Catalysts; 4.3 First Generation ZN Catalysts; 4.4 Second Generation ZN Catalysts; 4.5 Third Generation ZN Catalysts; 4.6 Fourth Generation ZN Catalysts; 4.7 Fifth Generation ZN Catalysts; 4.8 ZN Catalysts for Atactic Polypropylene; 4.9 Metallocenes and Other Single Site Catalysts; 4.10 Cocatalysts for ZN Catalysts
4.11 Kinetics and ZN Catalyst Productivity; 4.12 Concluding Remarks; 4.13 Questions; References; 5 Aluminum Alkyls in Ziegler-Natta Catalysts; 5.1 Organometallic Compounds; 5.2 Characteristics of Aluminum Alkyls; 5.2.1 Basic Physical and Chemical Properties; 5.2.2 Hydride Content; 5.2.3 Other R3A1 Impurities; 5.2.4 Analysis of Aluminum Alkyls; 5.2.5 Impurities Resulting from Exposure to Minute Concentrations of Water and Oxygen; 5.2.6 Assays of Aluminum Alkyls; 5.2.7 Reactivity with Organic Substrates; 5.2.8 Reactivity with CO2 and CO; 5.2.9 Distillation; 5.2.10 Association of Aluminum Alkyls
5.2.11 Storage Stability; 5.2.12 Thermal Stability; 5.3 Production of Aluminum Alkyls; 5.4 Reducing Agent for the Transition Metal; 5.5 Alkylating Agent for Creation of Active Centers; 5.6 Scavenger of Catalyst Poisons; 5.7 Chain Transfer Agent; 5.8 Safety and Handling of Aluminum Alkyls; 5.9 Questions; References; 6 Single Site Catalysts and Cocatalysts; 6.1 Introduction; 6.2 The Structures of Metallocenes and SSCs; 6.3 Non-Metallocene Polymerization Catalysts; 6.4 Cocatalysts for SSCs; 6.4.1 Aluminoxanes; 6.4.2 Organoboron Cocatalysts; 6.4.3 Activated Supports; 6.5 Supports for SSCs
6.6 Characteristics of mPP
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8
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This introductory text is an important resource for new engineers, chemists, students, and chemical industry personnel to understand the technical aspects of polypropylene which is the 2nd largest synthetics polymer in manufactured output. The book considers the following topics: What are the principal types of polypropylene and how do they differ? What catalysts are used to produce polypropylene and how do they function? What is the role of cocatalysts and how have they evolved over the years? How are industrial polypropylene catalysts tested and the resultant polymer evaluated? What proc
MIL
372268
Introduction to Industrial Polypropylene : Properties, Catalysts Processes
9781118062760
Polymerization.
Polymers.
Polypropylene.
Chemical engineering.
Engineering.
TEC-- 009010
668
.
4234
TP1180
.
P68
M36
2012
Malpass, Dennis B.
Band, Elliot I.
Ohio Library and Information Network.
Wiley Online Library (Online service)
20130111115437.0
rda
مطالعه متن کتاب [Book]
Y
