عنوان

Partition and adsorption of organic contaminants in environmental systems ]CD[

1776

Chiou, C. T. )Cary T.(

Partition and adsorption of organic contaminants in environmental systems ]CD[

Hoboken, N.J.

Wiley-Interscience

c2002

x, 257 p. : ill. ; 25 cm.

Includes bibliographical references )p. 235-248( and index

Machine generated contents note: 1 Important Thermodynamic Properties -- 1.1 Introduction 1 -- 1.2 First Law of Thermodynamics 2 -- 1.3 Second Law of Thermodynamics 3 -- 1.4 Extensive and Intensive Properties 6 -- 1.5 Chemical Potential 6 -- 1.6 Chemical Potentials in Multiple Phases 7 -- 1.7 Change in Chemical Potential with Pressure 8 -- 1.8 Activity of a Substance: 9 -- 1.9 Vapor-Liquid and Vapor-Solid Equilibria 01 -- 2 Fundamentals of the Solution Theory -- 2.1 Introduction 41 -- 2.2 Raoult's Law 41 -- 2.3 Henry's Law 81 -- 2.4 Flory-Huggins Theory 91 -- 2.5 Variation of Activity Coefficient with Concentration 12 -- 2.6 Molar Heat of Solution 22 -- 2.7 Cohesive Energy Density and Solubility Parameter 72 -- 3 Interphase Partition Equations -- 3.1 Partition between Two Separate Phases 03 -- 3.2 Partition between an Organic Solvent and Water 13 -- 3.3 Partition between a Macramolecular Phase and Water 23 -- 3.4 Temperature Dependence of Partition Coefficient 33 -- 3.5 Concentration Dependence of Partition Coefficient 63 -- 4 Fundamentals of the Adsorption Theory -- 4.1 Introduction 93 -- 4.2 Langmuir Adsorption Isotherm 14 -- 4.3 Freundlich Equation 34 -- 4.4 BET Multilayer Adsorption Theory 34 -- 4.5 Polanyi Adsorption Potential Theory 54 -- 4.6 Surface Areas of Solids 84 -- 4.7 Sosteric Heat of Adsorption 05 -- 5 Contaminant Partition and Bioconcentration -- 5.1 Introduction 35 -- 5.2 Octanol-Water Systems 45 -- 5.3 Heptane-Water Systems 95 -- 5.4 Butanol-Water Systems 26 -- 5.5 Substituent Contributions to Partition Coefficients 36 -- 5.6 Lipid-Water Systems 86 -- 5.6.1 Solubility of Solutes in Lipids 86 -- 5.6.2 Lipid-Water Partition Coefficient 27 -- 5.7 Correlations of Partition Coefficients 77 -- 5.8 Bioconcentration of Organic Contaminants 08 -- 6 Adsorption of Vapors on Minerals and Other Solids -- 6.1 Introduction 68 -- 6.2 Nitrogen Isotherm and Solid Surface Area 68 -- 6.3 Micropore Volume 09 -- 6.4 Imnproper Surface-Area Measurement 29 -- 6.5 Adsorption of Water and Organic Vapors 001 -- 7 Contaminant Sorption to Soils and Natural Solids -- 7.1 Introduction 601 -- 7.2 Background in Sorption Studies 701 -- 7.2.1 Influences of Mineral Matter, Organic Matter, and Water 701 -- 7.2.2 Soils as a Dual Sorbent for Organic Compounds 901 -- 7.3 Sorption from Water Solution 211 -- 7.3.1 General Equilibrium Characteristics 211 -- 7.3.2 Effect of Soil Organic Matter versus Sediment Organic Matter 421 -- 7.3.3 Effect of Contaminant Water Solubility 331 -- 7.3.4 Behavior of PAHs versus Other Nonpolar Contaminants 831 -- 7.3.5 Estimation of Sorption Coefficients for Nonpolar Contaminants 541 -- 7.3.6 Sorption to Previouy Contaminated Soils 641 -- 7.3.7 Deviations from Linear Sorption Isotherms 941 -- 7.3.8 Influence of Dissolv and Suspended Natural Organic Matter 81 -- 7.3.9 Influence of Surfactants and Microemulsions 871 -- 7.4 Sorption from Organic Solvents 291 -- 7.4.1 Effect of Solvent Polarity 291 -- 7.4.2 Effects of Temperature, Moisture, and Contaminant Polarity 591 -- 7.5 Sorption from Vapor Phase 002 -- 7.5.1 General Aspects of Vapor Sorption 002 -- 7.5.2 Influence of Moisture on Vapor Sorptiom 302 -- 7.6 Influence of Sorption on Contaminant Activity 012 -- 8 Contaminant Uptake by Plants from Soil and Water -- 8.1 Introduction 412 -- 8.2 Background in Plant-Uptake Studies 512 -- 8.3 Theoretical Considerations 612 -- 8.4 Uptake by Small Plant Roots from Water 022 -- 8.5 Uptake by Plant Seedlings from Soil 322 -- 8.6 Uptake by Root Crops from Different Soils 622 -- 8.7 Effect of Plant Composition 822 -- 8.8 Contaminant Levels in Aquatic Plants and Sediments 922 -- 8.9 Time Dependence of Contaminants in Plants 132

Environmental aspects ، Organic compounds

، Soil pollution

، Soil absorption and adsorption

AU

Cary T. Chiou

TI

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